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Stereodirected Synthesis with Organoboranes
Author
Title
Stereodirected Synthesis with Organoboranes [electronic resource] / by Donald S. Matteson.
ISBN
9783642797095
Publication
Berlin, Heidelberg : Springer Berlin Heidelberg, 1995.
Physical Description
1 online resource (XI, 405 p).
Local Notes
Access is available to the Yale community.
Access and use
Access restricted by licensing agreement.
Variant and related titles
Springer ENIN.
Other formats
Printed edition:
Printed edition:
Printed edition:
Format
Books / Online
Language
English
Added to Catalog
September 25, 2018
Series
Reactivity and Structure: Concepts in Organic Chemistry, 32
Contents
1 Introduction to Borane Chemistry
1.1 Beginnings
1.2 Structure and Bonding in Organoboranes
1.3 General Chemical Properties of Organoboranes
1.4 Safety Considerations
1.5 References
2 Sources of Compounds Containing Boron—Carbon Bonds
2.1 Industrial Sources of Boron Compounds
2.2 The Organometallic Route
2.3 Hydroboration
2.4 Haloborations
2.5 Other Routes to Carbon—Boron Bonds
2.6 References
3 General Reactions of Organoboranes
3.1 Introduction
3.2 Oxidative Replacement of Boron
3.3 Boron Substituted Carbanions
3.4 Replacement of Boron by Carbon
3.5 Reactions at Sites Other than the B-C Bond
3.6 References
4 Alkenylboranes and Control of Olefinic Geometry
4.1 Introduction
4.2 ?-Elimination Routes to Unsaturated Compounds
4.3 The Suzuki Coupling Reaction
4.4 Other Stereoselective Routes to Alkenes
4.5 References
5 Asymmetric Synthesis via (a-Haloalkyl)boronic Esters
5.1 Introduction
5.2 Synthetic Methodology: Pinanediol Esters
5.3 Synthetic Methodology: Chiral Directors Having C2 Symmetry
5.4 Synthetic Applications
5.5 References
6 Asymmetric Hydroboration Chemistry
6.1 Introduction
6.2 Asymmetric Hydroboration
6.3 Transformations of Asymmetric Organoboranes
6.4 Substrate Directed Hydroboration
6.5 Catalytic Asymmetric Hydroboration
6.6 References
7 Allylboron and Boron Enolate Chemistry
7.1 Introduction
7.2 Allylic Boronic Esters
7.3 Allyldialkylboranes
7.4 Boron Enolates
7.5 References
8 Diels-Alder Reactions
8.1 Introduction
8.2 Alkenylboranes
8.3 Butadienylboranes
8.4 Catalyzed Diels-Alder Reactions
8.5 References
9 Asymmetric Reductions and Miscellaneous Reactions
9.1 Introduction
9.2 Reductions with Alkylboranes
9.3 Reductions with Asymmetric B-H Compounds
9.4 Other Borane Catalyzed Reactions
9.5 Asymmetric Hydrozirconation
9.6 References
Author Index.
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