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Advances in organometallic chemistry. Volume 44
Title
Advances in organometallic chemistry. Volume 44 / edited by Robert West, Anthony F. Hill ; founding editor, F. Gordon A. Stone.
ISBN
9780080493725
0080493726
0120311445
9780120311446
Published
San Diego : Academic Press, [1999]
Physical Description
1 online resource (1 volume).
Local Notes
Access is available to the Yale community.
Access and use
Access restricted by licensing agreement.
Summary
This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.
Variant and related titles
Elsevier ScienceDirect All Books. OCLC KB.
Other formats
Print version: Advances in organometallic chemistry. Volume 44. San Diego : Academic Press, [1999]
Format
Books / Online
Language
English
Added to Catalog
September 08, 2020
Series
Advances in organometallic chemistry ; 44
Bibliography
Includes bibliographical references and index.
Contents
Front Cover; Advances in Organometallic Chemistry, Volume 44; Copyright Page; Contents; Contributors; Chapter 1. Element Derivatives of Sterically Encumbering Terphenyl Ligands; I. Introduction; II. Terphenyl Derivatives of s-Block Elements; III. Terphenyl Derivatives of d-Block and Group 12 Elements; IV. Terphenyl Derivatives of p-Block Elements; References; Chapter 2. Hydrogen Donor Abilities of the Group 14 Hydrides; I. Introduction; II. Bond Dissociation Energies and Kinetic Methods; III. Reactions of Radicals with Silicon Hydrides; IV. Reactions of Radicals with Germanium Hydrides
V. Reactions of Radicals with Tin HydridesVI. Kinetic Isotope Effects; VII. Comparisons of Reactivities of Group 14 Hydrides; VIII. Conclusion; References; Chapter 3. Doubly Bonded Derivatives of Germanium; I. Introduction; II. Germenes (>Ge=CGe=GeGe=SiSn=GeGe=N-); VII. Germaphosphenes (>Ge=P-); VIII. Germanones (>Ge=O); IX. Germanethiones (>Ge=S), Germaneselones (>Ge=Se), and Germanetellones (>Ge=Te); X. Germaallenes (>Ge=C=X); XI. Conclusion; References; Chapter 4. The Chemistry of Phosphinocarbenes
I. IntroductionII. Theoretical Studies; III. Synthesis; IV. Spectroscopic Data and X-Ray Analysis; V. Reactivity of Phosphinocarbenes R2P-C-X; VI. Ligand Properties of Phosphinocarbenes; VII. Conclusion; References; Chapter 5. Zwitterionic Pentacoordinate Silicon Compounds; I. Introduction; II. Acyclic ?5Si-Silicates with an SiF3C2 Skeleton; III. Spirocyclic 5Si-Silicates with an SiO4C Skeleton; IV. Spirocyclic ?5Si-Silicates with an SiO2N2C Skeleton; V. Spirocyclic ?5Si-Silicates with an SiO2S2C Skeleton; VI. Spirocyclic ?5Si-Silicates with an SiO5 Skeleton
VII. Monocyclic ?5Si-Silicates with an SiO2FC2 SkeletonVIII. Conclusions; References; Chapter 6. Transition Metal Complexes of Vlnylketenes; I. Introduction; II. ?4-(Vinylketene)Chromium(0) Complexes; III. ?4-(Vinylketene)Molybdenum and Tungsten Complexes; IV. ?4-(Vinylketene)Manganese(I) and ~4-(Vinylketene)Vanadium(I) Complexes; V. ?4-(Vinylketene)Cobalt(i) Complexes; VI. ?4-(Vinylketene)Iron(0) Complexes; VII. Conclusion; References; Subject Index; Cumulative List of Contributors for Volumes 1-36; Cumulative Index for Volumes 37-44
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