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Advances in organometallic chemistry. Volume 41
Title
Advances in organometallic chemistry. Volume 41 / edited by F. Gordon A. Stone, Robert West.
ISBN
9780080580425
0080580424
0120311410
9780120311415
9780120311415
Published
San Diego : Academic Press, ©1997.
Physical Description
1 online resource (1 volume) : illustrations.
Local Notes
Access is available to the Yale community.
Access and use
Access restricted by licensing agreement.
Summary
This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambienttemperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. This book is an essential reference work for the academic and industrial chemist and will provide up-to-date material at the cutting edge of chemistry research. Key Features * In basic research, organometallics have contributed inter alia to: * Metal cluster chemistry * Surface chemistry * The stabilization of highly reactive species by metal coordination * Chiral synthesis * The formulation of multiple bonds between carbon and the other elements and between the elements themselves * Metal organic compounds of calcium, strontium, and barium in chemical vapor deposition * 17- and 19-electron organometallic complexes * Halocarbonyl complexes of molybdenum and tungsten * Substituent effects in metallacene chemistry.
Variant and related titles
Elsevier ScienceDirect All Books. OCLC KB.
Other formats
Print version: Advances in organometallic chemistry. Volume 41. San Diego : Academic Press, ©1997
Format
Books / Online
Language
English
Added to Catalog
September 08, 2020
Series
Advances in organometallic chemistry ; 41
Bibliography
Includes bibliographical references and index.
Contents
Front Cover; Advances in Organometallic Chemistry, Volume 41; Copyright Page; Contents; Contributors; Chapter 1. Transition-Metal Assisted Syntheses of Rings and Cages from Phosphaalkenes and Phosphaalkynes; I. Introduction; II. Phosphaalkenes as Ligands in Transition-Metal Complexes; III. Rings and Cages from Phosphaalkenes; IV. Phosphaalkynes as Ligands in Transition-Metal Complexes; V. Rings and Cages from Phosphaalkynes; VI. Conclusions and Prospects; VII. Abbreviations Used in This Review; References; Chapter 2. Synthesis and Reactions of Polynuclear Cobalt-Alkyne Complexes
I. IntroductionII. Dinuclear Complexes; III. Trinuclear Clusters; IV. Tetranuclear Complexes; V. Higher Nuclearity Complexes; VI. Applications; VII. Conclusions; References; Chapter 3. Rhenium and Technetium Oxo Complexes in the Study of Organic Oxidation Mechanisms; I. Introduction; II. Methyl Rhenium Trioxide (MTO); III. Bishydroxylation of Alkenes; IV. Conclusions; References; Chapter 4. (1 -Alkynyl)carbene Complexes (= 1-Metalla-1-buten-3-ynes): Tools for Synthesis; I. Introduction; II. Preparation, Spectroscopic and Structural Data; III. Reaction with Carbon Nucleophiles (and Homologs)
IV. Reaction with Nitrogen and Phosphorus NucleophilesV. Reaction with Oxygen and Sulfur Nucleophiles; VI. 1-Alkynyl Acylmetallates; VII. Metallation/Transmetallation; VIII. 1,2-Elimination with Formation of Alkynyl Carbyne Complexes; References; Chapter 5. Chalcogen-Bridged Metal-Carbonyl Complexes; I. Introduction; II. Cationic Clusters; III. Anionic Clusters; IV. Neutral Clusters; References; Index; Comulative List of Contributors for Volumes 1-36; Cumulative Index for Volumes 37-41
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