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Advances in Chemistry Series ; 230

Reaction Monitoring by High-Pressure Cylindrical Internal-Reflectance and Optical-Fiber Coupled Reactors / Moser, William R. / http://dx.doi.org/10.1021/ba-1992-0230.ch001

In Situ Spectroscopic Studies in Homogeneous Catalysis / Whyman, Robin / http://dx.doi.org/10.1021/ba-1992-0230.ch002

NMR Techniques for Studies of Homogeneous Catalysis / Roe, D. Christopher / http://dx.doi.org/10.1021/ba-1992-0230.ch003

Parahydrogen-Induced Polarization and Polarization Transfer in Hydrogenation and Oxidative Addition Reactions: A Mechanistic Probe / Eisenberg, Richard; Eisenschmid, Thomas C.; Chinn, Mitchell S.; Kirss, Rein U. / http://dx.doi.org/10.1021/ba-1992-0230.ch004

The Tricarbonylhydridocobalt-Based Hydroformylation Reaction: A Theoretical Study / Ziegler, Tom; Versluis, Louis / http://dx.doi.org/10.1021/ba-1992-0230.ch005

Oscillations and Chaos in Some O2 Oxidations / Druliner, J. D., Central Research and Development, E. I. du Pont de Nemours and Company, Experimental Station, P.O. Box 80328, Wilmington, DE 19880-0328; Greller, L. D., SmithKline Beecham, P.O. Box 1539, King of Prussia, PA 19406-0939; Roelofs, M. G., Central Research and Development, E. I. du Pont de Nemours and Company, Experimental Station, P.O. Box 80328, Wilmington, DE 19880-0328; Wasserman, E., Central Research and Development, E. I. du Pont de Nemours and Company, Experimental Station, P.O. Box 80328, Wilmington, DE 19880-0328 / http://dx.doi.org/10.1021/ba-1992-0230.ch006

Flash Photolysis Studies of Reactive Organometallic Intermediates Relevant to Homogeneous Catalysis / Ford, Peter C.; Belt, Simon T. / http://dx.doi.org/10.1021/ba-1992-0230.ch007

New 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl-Ru(II) Complexes for Asymmetric Catalytic Hydrogenation / Takaya, Hidemasa; Ohta, Tetsuo; Mashima, Kazushi / http://dx.doi.org/10.1021/ba-1992-0230.ch008

Enantioselective Catalysis with Transition Metal Compounds: Right or Left-This Is the Question / Brunner, Henri / http://dx.doi.org/10.1021/ba-1992-0230.ch009

Shape-Selective Olefin Epoxidation Catalyzed by Metallo "Picnic-Basket" Porphyrins / Collman, James P., Department of Chemistry, Stanford University, Stanford, CA 94305; Zhang, Xumu, Department of Chemistry, Stanford University, Stanford, CA 94305; Lee, Virgil, Department of Chemistry, Stanford University, Stanford, CA 94305; Hembre, Robert T., Department of Chemistry, University of Nebraska, Lincoln, NE 68588; Brauman, John I., Department of Chemistry, Stanford University, Stanford, CA 94305 / http://dx.doi.org/10.1021/ba-1992-0230.ch010

Stereocontrol in Catalyzed and Uncatalyzed Hydroborations / Burgess, Kevin; Ohlmeyer, Michael J. / http://dx.doi.org/10.1021/ba-1992-0230.ch011

Functionalization of Hydrocarbons by Homogeneous Catalysis / Tanaka, Masato; Sakakura, Toshiyasu / http://dx.doi.org/10.1021/ba-1992-0230.ch012

Mercury-Photosensitized C-H Bond Functionalization / Crabtree, Robert H.; Brown, Steven H.; Muedas, Cesar A.; Krajnik, Paul; Ferguson, Richard R. / http://dx.doi.org/10.1021/ba-1992-0230.ch013

Activation of Carbon-Hydrogen Bonds in Alkanes and Other Organic Molecules Using Organotransition Metal Complexes / Bergman, Robert G. / http://dx.doi.org/10.1021/ba-1992-0230.ch014

Selective Hydroxylation of Hydrocarbons by Platinum Salts in Aqueous Media: Direct Conversion of Ethanol to Ethylene Glycol / Labinger, Jay A.; Herring, Andrew M.; Bercaw, John E. / http://dx.doi.org/10.1021/ba-1992-0230.ch015

Amidocarbonylation: Catalyst, Reaction Scope, and Industrial Application / Lin, J. J., Current address: Shell Development Company, P.O. Box 1380, Houston, TX 77251; Knifton, J. F. / http://dx.doi.org/10.1021/ba-1992-0230.ch016

Activation of Carbon Monoxide by Metalloradicals / Wayland, Bradford B.; Sherry, Alan E.; Coffin, Virginia L. / http://dx.doi.org/10.1021/ba-1992-0230.ch017

Electrochemical vs. Chemical Synthesis of Homogeneous Catalysts for Regio- and Enantioselective Olefin Hydroformylation / Mortreux, André; Petit, Francis / http://dx.doi.org/10.1021/ba-1992-0230.ch018

New Carbonylations Catalyzed by Transition Metal Complexes / Ojima, Iwao; Zhang, Zhaoda; Korda, Anna; Ingallina, Patrizia; Clos, Nuria / http://dx.doi.org/10.1021/ba-1992-0230.ch019

Tetracarbonylalkylcobalts from Tetracarbonylhydridocobalt and Dimethyl Fumarate or Aldehydes / Ungváry, Ferenc; Sisak, Attila; Markó, László / http://dx.doi.org/10.1021/ba-1992-0230.ch020

Oxides as Heterogeneous Promoters for Liquid-Phase Hydrocarbonylation Reactions with Iodocarbonylruthenium Catalysts / Braca, Giuseppe, Department of Chemistry, University of Pisa, 56126 Pisa, Italy; Galletti, Anna Maria Raspolli, Department of Chemistry, University of Pisa, 56126 Pisa, Italy; Sbrana, Glauco, Department of Chemistry, University of Pisa, 56126 Pisa, Italy; Trabuco, Elizeu, Instituto de Biocencias, Letras e Ciencias Exatas, Universidade Estadual Paulista, San Jose do Rio Preto, Brazil / http://dx.doi.org/10.1021/ba-1992-0230.ch021

Rhodium-Catalyzed Reductive Carbonylation of Methanol / Moloy, Kenneth G.; Wegman, Richard W. / http://dx.doi.org/10.1021/ba-1992-0230.ch022

Hydrogen Activation by Soluble Metal Oxide Complexes / Klingler, R. J.; Krause, T. R.; Rathke, J. W. / http://dx.doi.org/10.1021/ba-1992-0230.ch023

Homogeneous Bimetallic Hydroformylation Catalysis: Two Metals Are Better Than One / Laneman, Scott A.; Stanley, George G. / http://dx.doi.org/10.1021/ba-1992-0230.ch024

Hydroformylation and Hydrogenation with Platinum Phosphinito Complexes / van Leeuwen, Piet W. N. M.; Roobeek, Cornelis F. / http://dx.doi.org/10.1021/ba-1992-0230.ch025

Rhodium-Catalyzed Carbonylation of Methyl Acetate / Zoeller, Joseph R., Research Laboratories, Eastman Chemical Company, Kingsport, TN 37662; Cloyd, James D., Research Laboratories, Eastman Chemical Company, Kingsport, TN 37662; Lafferty, Norma L., Research Laboratories, Eastman Chemical Company, Kingsport, TN 37662; Nicely, Vincent A., Research Laboratories, Eastman Chemical Company, Kingsport, TN 37662; Polichnowski, Stanley W., Research Laboratories, Eastman Chemical Company, Kingsport, TN 37662; Cook, Steven L., Tennessee Eastman Acid Division, Eastman Chemical Company, Kingsport, TN 37662 / http://dx.doi.org/10.1021/ba-1992-0230.ch026

Electronic Effects on the Synthesis, Structure, Reactivity, and Selectivity of Rhodium Hydroformylation Catalysts / Oswald, Alexis A., Enimont America, Inc., R&D Center, Monmouth Junction, NJ 08852; Hendriksen, Dan E., Exxon Chemical Company, Baytown, TX 77522-4900; Kastrup, Rodney V., Exxon Research and Engineering Company, Annandale, NJ 08801; Mozeleski, Edmund J., Exxon Chemical Company, Annandale, NJ 08801 / http://dx.doi.org/10.1021/ba-1992-0230.ch027

Influence of Organophosphines on the Hydroformylation of Olefins Catalyzed by Anionic Ruthenium Clusters / Süss-Fink, Georg / http://dx.doi.org/10.1021/ba-1992-0230.ch028

Selectivity Control in the Animation of Ethylene Glycol / Marsella, John A. / http://dx.doi.org/10.1021/ba-1992-0230.ch029

Electronic and Steric Control: Catalytic Intramolecular Carbon-Hydrogen Insertion Reactions of Diazo Compounds / Doyle, Michael P. / http://dx.doi.org/10.1021/ba-1992-0230.ch030

Cyclizations Made Easy by Transition Metal Catalysts / Trost, Barry M. / http://dx.doi.org/10.1021/ba-1992-0230.ch031

Classic Process Chemistry: New Science and New Applications / Nugent, William A.; McKinney, Ronald J.; Hobbs, Frank W.; Waller, Francis J. / http://dx.doi.org/10.1021/ba-1992-0230.ch032

Catalyzed and Noncatalyzed Hydrosilation of Organotransition Metal Acyl Complexes / Hanna, Paul K.; Gregg, Brian T.; Tarazano, D. Lawrence; Pinkes, John R.; Cutler, Alan R. / http://dx.doi.org/10.1021/ba-1992-0230.ch033

Reduction of Methanol by Tetracarbonylcobalt Anion Assisted by Carbon Dioxide and Cobalt Cation / Fachinetti, Giuseppe; Funaioli, Tiziana / http://dx.doi.org/10.1021/ba-1992-0230.ch034

The Activation of Carbon-Oxygen Bonds: Approaches to the Catalytic Deoxygenation of Phenols by CO / Ni, J.; Kubiak, C. P. / http://dx.doi.org/10.1021/ba-1992-0230.ch035

High-Velocity Palladium Catalysis / Friebe, Timothy L., Department of Chemistry, Northwestern University, Evanston, IL 60208; Johnson, John R., Department of Chemistry, Northwestern University, Evanston, IL 60208; Krysan, Damian J., Department of Chemistry, Northwestern University, Evanston, IL 60208; Mackenzi, Peter B., Department of Chemistry, Northwestern University, Evanston, IL 60208; Sabat, Michal, Department of Chemistry, University of Virginia, Charlottesville, VA 22903 / http://dx.doi.org/10.1021/ba-1992-0230.ch036

Hydrosilylation: A "Homogeneous" Reaction Really Catalyzed by Colloids / Lewis, Larry N.; Lewis, Nathan, Current address: Knolls Atomic Power Laboratory, Niskayuna, NY 12309; Uriarte, Richard J., Current address: G E Silicone, Waterford, NY 12188 / http://dx.doi.org/10.1021/ba-1992-0230.ch037

Catalytic Synthesis of Polymethylsilsesquioxanes / Laine, Richard M., Department of Materials Science and Engineering, University of Washington, Seattle, WA 98195, Corresponding author: Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109-2136; Rahn, Jeffrey A., Department of Materials Science and Engineering, University of Washington, Seattle, WA 98195, Current address: Department of Chemistry, Eastern Washington University, Cheney, WA 99004; Blohowiak, Kay Youngdahl, Department of Materials Science and Engineering, University of Washington, Seattle, WA 98195; Harrod, John F., Department of Chemistry, McGill University, Montreal H3A 2A7, Canada / http://dx.doi.org/10.1021/ba-1992-0230.ch038

Model Systems for Catalytic Reactions / Maitlis, Peter M.; Ma, Futai; Martinez, Jesus; Byers, Peter K.; Saez, Isabel; Sunley, Glenn J. / http://dx.doi.org/10.1021/ba-1992-0230.ch039

Active Sites in Soluble Ziegler Polymerization Catalysts Generated from Titanocene Halides and Organoaluminum Lewis Acids / Eisch, J. J.; Caldwell, K. R. / http://dx.doi.org/10.1021/ba-1992-0230.ch040

Homogeneous Chromium Catalysts for Olefin Polymerization / Theopold, K. H.; Heintz, R. A.; Noh, S. K.; Thomas, B. J. / http://dx.doi.org/10.1021/ba-1992-0230.ch041

Homogeneous catalysis > Monitoring > Methodology.

Homogeneous catalysis > Spectra.

Nuclear magnetic resonance spectroscopy > Utilization.

Hydrogenation > Analysis.

Hydroformylation > Testing.

Benzaldehyde > Oxidation > Properties.

Organometallic compounds > Experiments.

Flash photolysis > Utilization.

Enantioselective catalysis > Experiments.

Organic compounds > Synthesis.

Organotransition metal compounds > Utilization.

Synthesis gas > Formation > Technique.

Carbon monoxide > Reactivity > Mechanism of action.

Homogeneous catalysts > Mechanism of action.

Transition metal catalysts > Experiments.

Oxides > Utilization.

Rhodium catalysts > Utilization.

Rhodium catalysts > Variation.

Acetic acid > Formation.

Rhodium catalysts > Reactivity.

Alkenes > Reactivity.

Ethylene glycol > Reactivity.

Diazo compounds > Composition.

Chemicals > Synthesis > Purification > Methodology.

Hydrosilation > Methodology.

Methanol > Experiments.

Carbon monoxide > Utilization.

Palladium catalysts > Properties.

Colloids > Formation.

Copolymers > Formation.

Catalysis > Models.

Polyethylene > Synthesis.

Metals.

Catalysis.

Optical Fibers.

Spectrum Analysis.

Magnetic Resonance Spectroscopy.

Hydrogenation.

Oxidation-Reduction.

Photolysis.

Organometallic Compounds - analysis.

Alkenes.

Porphyrins.

Hydrogen Bonding.

Boron.

Carbon.

Alkanes.

Coordination Complexes.

Hydroxylation.

Platinum.

Ethanol.

Ethylene Glycol.

Carbon Monoxide.

Dimethyl Fumarate.

Aldehydes.

Rhodium.

Methanol - chemistry.

Acetates - chemistry.

Ruthenium.

Cyclization.

Cations.

Cobalt.

Palladium.

Colloids.

Polymerization.

Lewis Acids.

Chromium.

American Chemical Society. Meeting (199th : 1990 : Boston, Massachusetts)

American Chemical Society. Catalysis and Surface Science Secretariat, sponsoring body.