"Developed from a symposium sponsored by the Division of Geochemistry, Inc., at the 204th National Meeting of the American Chemical Society, Washington, DC, August 23-28, 1992."

Distributed in print by Oxford University Press.

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Original

Online version

Original

ACS symposium series, 550

Rates of Reaction of Galena, Sphalerite, Chalcopyrite, and Arsenopyrite with Fe(III) in Acidic Solutions / Rimstidt, J. Donald, Department of Geological Sciences, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061; Chermak, John A., Mineralogisches Institut, Universität Bern, 3012 Bern, Switzerland; Gagen, Patrick M., O.H.M. Corporation, 1000 Holcomb Woods Parkway, Roswell, GA 30076 / http://dx.doi.org/10.1021/bk-1994-0550.ch001

Laboratory Studies of Pyrrhotite Oxidation Kinetics / Nicholson, Ronald V., Department of Earth Sciences, Waterloo Centre for Groundwater Research, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada; Scharer, Jeno M., Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada / http://dx.doi.org/10.1021/bk-1994-0550.ch002

Effect of Humidity on Pyrite Oxidation / Borek, Sandra L. / http://dx.doi.org/10.1021/bk-1994-0550.ch003

Kinetics of Hydrothermal Enrichment of Chalcopyrite / Jang, Joon H., Current address: Pohang Iron and Steel Company, Pohang, Kyung Puk, South Korea; Wadsworth, Milton E. / http://dx.doi.org/10.1021/bk-1994-0550.ch004

Oxidation of Inorganic Sulfur Compounds by Thiobacilli / Suzuki, Isamu; Chan, C. W.; Takeuchi, T. L. / http://dx.doi.org/10.1021/bk-1994-0550.ch005

Microbial Oxidation of Sulfides by Thiobacillus denitrificans for Treatment of Sour Water and Sour Gases / Sublette, K. L., Center for Environmental Research and Technology, University of Tulsa, 600 South College Avenue, Tulsa, OK 74104; McInerney, Michael J., Department of Botany and Microbiology, University of Oklahoma, 770 van Vleet Oval, Norman, OK 73019; Montgomery, Anne D., Department of Botany and Microbiology, University of Oklahoma, 770 van Vleet Oval, Norman, OK 73019; Bhupathiraju, Vishveshk, Department of Botany and Microbiology, University of Oklahoma, 770 van Vleet Oval, Norman, OK 73019 / http://dx.doi.org/10.1021/bk-1994-0550.ch006

Solid-Phase Alteration and Iron Transformation in Column Bioleaching of a Complex Sulfide Ore / Ahonen, Lasse, Geological Survey of Finland, SF-02150 Espoo, Finland; Tuovinen, Olli H., Department of Microbiology, Ohio State University, 484 West 12th Avenue, Columbus, OH 43210-1292 / http://dx.doi.org/10.1021/bk-1994-0550.ch007

Alteration of Mica and Feldspar Associated with the Microbiological Oxidation of Pyrrhotite and Pyrite / Bhatti, Tariq M., Department of Microbiology, Ohio State University, 484 West 12th Avenue, Columbus, OH 43210-1292, Current address: National Institute of Biotechnology and Genetic Engineering, P.O. Box 577, Faisalabad, Pakistan; Bigham, Jerry M., Department of Agronomy, Ohio State University, 2021 Coffey Road, Columbus, OH 43210; Vuorinen, Antti, Department of Geology, University of Helsinki, P.O. Box 115, SF-00171 Helsinki, Finland; Tuovinen, Olli H., Department of Microbiology, Ohio State University, 484 West 12th Avenue, Columbus, OH 43210-1292 / http://dx.doi.org/10.1021/bk-1994-0550.ch008

Rates of Mechanisms That Govern Pollutant Generation from Pyritic Wastes / Ritchie, A. I. M. / http://dx.doi.org/10.1021/bk-1994-0550.ch009

Attempts To Model the Industrial-Scale Leaching of Copper-Bearing Mine Waste / Cathles, L. M. / http://dx.doi.org/10.1021/bk-1994-0550.ch010

A Computer Program To Assess Acid Generation in Pyritic Tailings / Scharer, Jeno M., Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada; Nicholson, Ronald V., Department of Earth Sciences, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada; Halbert, Bruce, SENES Consultants Ltd., 52 West Beaver Creek Road, Richmond Hill, Ontario L4B 1L9, Canada; Snodgrass, William J., Department of Civil Engineering, McMaster University, Hamilton, Ontario L8S 4M1, Canada / http://dx.doi.org/10.1021/bk-1994-0550.ch011

Time-Space Continuum Formulation of Supergene Enrichment and Weathering of Sulfide-Bearing Ore Deposits / Lichtner, Peter C., Current address: Southwest Research Institute, Center for Nuclear Waste Regulatory Analyses, 6220 Culebra Road, San Antonio, TX 78238-5166 / http://dx.doi.org/10.1021/bk-1994-0550.ch012

Influence of Siderite on the Pore-Water Chemistry of Inactive Mine-Tailings Impoundments / Ptacek, C. J., National Water Research Institute, 867 Lakeshore Road, P.O. Box 5050, Burlington, Ontario L7R 4A6, Canada, Waterloo Centre for Groundwater Research, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada; Blowes, David W., Waterloo Centre for Groundwater Research, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada / http://dx.doi.org/10.1021/bk-1994-0550.ch013

Mineralogical Characteristics of Poorly Crystallized Precipitates Formed by Oxidation of Fe2+ in Acid Sulfate Waters / Murad, E., Lehrstuhl für Bodenkunde, Technische Universität München, D-85350 Freising-Weihenstephan, Germany, Current address: Bayerisches Geologisches Landesamt, Concordiastrasse 28, D-96049 Bamberg, Germany; Schwertmann, U., Lehrstuhl für Bodenkunde, Technische Universität München, D-85350 Freising-Weihenstephan, Germany; Bigham, Jerry M., Department of Agronomy, Ohio State University, Columbus, OH 43210-1086; Carlson, L., Department of Geology, University of Helsinki, SF-00171 Helsinki, Finland / http://dx.doi.org/10.1021/bk-1994-0550.ch014

Atomic and Electronic Structure of PbS {100} Surfaces and Chemisorption-Oxidation Reactions / Eggleston, Carrick M., Institute for Water Resources and Water Pollution Control, Swiss Federal Institutes of Technology, CH-8600 Dubendorf, Switzerland; Hochella, Michael F., Department of Geological Sciences, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061 / http://dx.doi.org/10.1021/bk-1994-0550.ch015

Effects of Instream pH Modification on Transport of Sulfide-Oxidation Products / Kimball, Briant A., U.S. Geological Survey, 1745 West 1700 South, Room 1016, Salt Lake City, UT, 84104; Broshears, Robert E., U.S. Geological Survey, Box 25046, MS 415, Denver, CO 80225; McKnight, Diane M., U.S. Geological Survey, Box 25046, MS 415, Denver, CO 80225; Bencala, Kenneth E., U.S. Geological Survey, 345 Middlefield Road, MS 496, Menlo Park, CA 94025 / http://dx.doi.org/10.1021/bk-1994-0550.ch016

Transport and Natural Attenuation of Cu, Zn, As, and Fe in the Acid Mine Drainage of Leviathan and Bryant Creeks / Webster, Jenny G., Institute of Environmental Health and Forensic Science, P.O. Box 92021, Auckland, New Zealand; Nordstrom, D. Kirk, U.S. Geological Survey, 3215 Marine Street, Boulder, CO 80303; Smith, Kathleen S., U.S. Geological Survey, MS 973, Denver Federal Center, Denver, CO 80225 / http://dx.doi.org/10.1021/bk-1994-0550.ch017

Acid Mine Drainage in Wales and Influence of Ochre Precipitation on Water Chemistry / Fuge, Ron; Pearce, Fiona M.; Pearce, Nicholas J. G.; Perkins, William T. / http://dx.doi.org/10.1021/bk-1994-0550.ch018

Stratigraphy and Chemistry of Sulfidic Flood-Plain Sediments in the Upper Clark Fork Valley, Montana / Nimick, David A., Water Resources Division, U.S. Geological Survey, Helena, MT 59626; Moore, Johnnie N., Department of Geology, University of Montana, Missoula, MT 59812 / http://dx.doi.org/10.1021/bk-1994-0550.ch019

Release of Toxic Metals via Oxidation of Authigenic Pyrite in Resuspended Sediments / Morse, John W. / http://dx.doi.org/10.1021/bk-1994-0550.ch020

Mobilization and Scavenging of Heavy Metals Following Resuspension of Anoxic Sediments from the Elbe River / Calmano, W.; Förstner, U.; Hong, J., Current address: Department of Chemical Engineering, Tulane University, New Orleans, LA 70118 / http://dx.doi.org/10.1021/bk-1994-0550.ch021

Seasonal Variations of Zn/Cu Ratios in Acid Mine Water from Iron Mountain, California / Alpers, Charles N., Water Resources Division, U.S. Geological Survey, Federal Building, Room W-2233, 2800 Cottage Way, Sacramento, CA 95825; Nordstrom, D. Kirk, Water Resources Division, U.S. Geological Survey, 3215 Marine Street, Boulder, CO 80303; Thompson, J. Michael, Geologic Division, U.S. Geological Survey, Branch of Volcanic and Geothermal Processes, MS-910, 345 Middlefield Road, Menlo Park, CA 94025 / http://dx.doi.org/10.1021/bk-1994-0550.ch022

Secondary Iron-Sulfate Minerals as Sources of Sulfate and Acidity: Geochemical Evolution of Acidic Ground Water at a Reclaimed Surface Coal Mine in Pennsylvania / Cravotta, C. A. / http://dx.doi.org/10.1021/bk-1994-0550.ch023

Limit to Self-Neutralization in Acid Mine Tailings: The Case of East Sullivan, Quebec, Canada / Germain, M. D.; Tassé, N.; Bergeron, M. / http://dx.doi.org/10.1021/bk-1994-0550.ch024

Attenuation of Acid Rock Drainage in a Natural Wetland System / Kwong, Y. T. J.; Van Stempvoort, D. R., Current address: Saskatchewan Research Council, 15 Innovation Boulevard, Saskatoon, Saskatchewan S7N 2X8, Canada / http://dx.doi.org/10.1021/bk-1994-0550.ch025

Kinetics of Oxidation of Hydrogen Sulfide in Natural Waters / Zhang, Jia-Zhong; Millero, Frank J. / http://dx.doi.org/10.1021/bk-1994-0550.ch026

Determination of Hydrogen Sulfide Oxidation Products by Sulfur K-Edge X-ray Absorption Near-Edge Structure Spectroscopy / Vairavamurthy, Appathurai; Manowitz, Bernard; Zhou, Weiqing; Jeon, Yongseog, Current address: Department of Physics, Jeonju University, Hyojadong 3-ga 1200, Wansan-gu, Jeonju, Seoul 560-759, Korea / http://dx.doi.org/10.1021/bk-1994-0550.ch027

Evolved-Gas Analysis: A Method for Determining Pyrite, Marcasite, and Alkaline-Earth Carbonates / Hammack, Richard W. / http://dx.doi.org/10.1021/bk-1994-0550.ch028

Controls of δ18O in Sulfate: Review of Experimental Data and Application to Specific Environments / Van Stempvoort, D. R., National Hydrology Research Institute, 11 Innovation Boulevard, Saskatoon, Saskatchewan S7N 3H5, Canada, Current address: Saskatchewan Research Council, 15 Innovation Boulevard, Saskatoon, Saskatchewan S7N 2X8, Canada; Krouse, H. R., Department of Physics and Astronomy, University of Calgary, 2500 University Drive Northwest, Calgary, Alberta T2N 1N4, Canada / http://dx.doi.org/10.1021/bk-1994-0550.ch029

Sulfur- and Oxygen-Isotope Geochemistry of Acid Mine Drainage in the Western United States: Field and Experimental Studies Revisited / Taylor, B. E., Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario K1A 0E8, Canada; Wheeler, Mark C., Groundworks Environmental, Inc., 1022 North Second Street, San Jose, CA 95112 / http://dx.doi.org/10.1021/bk-1994-0550.ch030

Applications of Mass-Balance Calculations to Weathered Sulfide Mine Tailings / Appleyard, Edward C.; Blowes, David W. / http://dx.doi.org/10.1021/bk-1994-0550.ch031

Oxidation of Massive Sulfide Deposits in the Bathurst Mining Camp, New Brunswick: Natural Analogues for Acid Drainage in Temperate Climates / Boyle, D. R. / http://dx.doi.org/10.1021/bk-1994-0550.ch032

Thiosulfate Complexing of Platinum Group Elements: Implications for Supergene Geochemistry / Anthony, Elizabeth Y., Department of Geological Sciences, University of Texas at El Paso, El Paso, TX 79968; Williams, Peter A., Department of Chemistry, University of Western Sydney, Nepean, P.O. Box 10, Kingswood, New South Wales 2747, Australia / http://dx.doi.org/10.1021/bk-1994-0550.ch033

Suppression of Pyrite Oxidation Rate by Phosphate Addition / Huang, Xiao, Department of Agronomy, University of Kentucky, N-122 Agricultural Science Center North, Lexington, KY 40546-0091, Pittsburgh Research Center, U.S. Bureau of Mines, Pittsburgh, PA 15236; Evangelou, V. P., Department of Agronomy, University of Kentucky, N-122 Agricultural Science Center North, Lexington, KY 40546-0091, Department of Agricultural Experiment Station, University of Kentucky, N-122 Agricultural Science Center North, Lexington, KY 40546-0091, Pittsburgh Research Center, U.S. Bureau of Mines, Pittsburgh, PA 15236 / http://dx.doi.org/10.1021/bk-1994-0550.ch034

Iron Sulfide Oxidation: Impact on Chemistry of Leachates from Natural and Pyrolyzed Organic-Rich Shales / Robl, Thomas L. / http://dx.doi.org/10.1021/bk-1994-0550.ch035

Oxidation of Sulfide Minerals Present in Duluth Complex Rock: A Laboratory Study / Lapakko, Kim A.; Antonson, David A. / http://dx.doi.org/10.1021/bk-1994-0550.ch036

Chemical Predictive Modeling of Acid Mine Drainage from Metallic Sulfide-Bearing Waste Rock / White, W. W.; Jeffers, T. H. / http://dx.doi.org/10.1021/bk-1994-0550.ch037

Composition of Interstitial Gases in Wood Chips Deposited on Reactive Mine Tailings: Consequences for Their Use as an Oxygen Barrier / Tassé, N.; Germain, M. D.; Bergeron, M. / http://dx.doi.org/10.1021/bk-1994-0550.ch038

Field Research on Thermal Anomalies Indicating Sulflde-Oxidation Reactions in Mine Spoil / Guo, Weixing; Parizek, Richard R. / http://dx.doi.org/10.1021/bk-1994-0550.ch039

Sulfides > Oxidation > Environmental aspects.

Chemical kinetics > Tables.

Pyrrhotite > Oxidation > Mechanism of action.

Pyrites > Oxidation.

Chalcopyrite > Mechanism of action.

Thiobacillus > Analysis.

Pyrites > By-products.

Siderite > Dissolution.

Mössbauer spectroscopy > Application.

Galena > Surfaces.

Mine drainage > California.

Mine drainage > Nevada.

Acid mine drainage > California.

Acid mine drainage > Colorado.

Mine drainage > Wales.

Abandoned mines > Wales.

Floodplains > Montana.

Heavy metals > Oxidation.

Elbe River (Czech Republic and Germany) > Measurement.

Mine water > California.

Hydrogen sulfide > Oxidation > Mechanism of action.

X-ray absorption near edge structure > Application.

Thiosulfates > Analysis.

Oil-shales > Analysis.

Sulfide minerals > Oxidation.

Mine soils > Pennsylvania.

Sulfides - chemistry.

Oxidation-Reduction.

Water - chemistry.

Coal Mining.

Copper - analysis.

Oxidation-Reduction.

Iron - chemistry.

Thiobacillus.

Aluminum Silicates.

Carbonates - analysis.

Ferric Compounds - analysis.

Hydrogen-Ion Concentration.

Metals - toxicity.

Metals, Heavy - metabolism.

Sulfates.

Groundwater - analysis.

Pennsylvania.

Quebec.

Wetlands.

Hydrogen Sulfide - pharmacokinetics.

X-Ray Absorption Spectroscopy.

Oxygen Isotopes - chemistry.

Sulfur Isotopes - chemistry.

Thiosulfates.

Platinum.

Phosphates.

Water Pollutants, Chemical - chemistry.

Gases - chemistry.

American Chemical Society. Division of Geochemistry, sponsoring body.

American Chemical Society. Meeting (204th : 1992 : Washington, D.C.)