"Developed from a symposium sponsored by the Division of Geochemistry, Inc., at the 208th National Meeting of the American Chemical Society, Washington, D.C., August 21-25, 1994."

Distributed in print by Oxford University Press.

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Original

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ACS symposium series, 612

Geochemical Transformations of Sedimentary Sulfur: An Introduction / Vairavamurthy, Murthy A., Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973; Orr, Wilson L., Earth and Energy Science Advisors, P.O. Box 3729, Dallas, TX 75208; Manowitz, Bernard, Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973 / http://dx.doi.org/10.1021/bk-1995-0612.ch001

Role of Sulfur in the Transformations of Sedimentary Organic Matter: A Mechanistic Overview / Aizenshtat, Zeev, Department of Organic Chemistry and Casali Institute for Applied Chemistry, Energy Research Center, Hebrew University of Jerusalem, Jerusalem 91904, Israel; Krein, Eitan B., Department of Organic Chemistry and Casali Institute for Applied Chemistry, Energy Research Center, Hebrew University of Jerusalem, Jerusalem 91904, Israel; Vairavamurthy, Murthy A., Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973; Goldstein, Ted P., Department of Organic Chemistry and Casali Institute for Applied Chemistry, Energy Research Center, Hebrew University of Jerusalem, Jerusalem 91904, Israel / http://dx.doi.org/10.1021/bk-1995-0612.ch002

Sulfur Transformations in Early Diagenetic Sediments from the Bay of Conception, Off Chile / Vairavamurthy, Murthy A., Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973; Wang, Shengke, Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973; Khandelwal, Bandana, Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973; Manowitz, Bernard, Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973; Ferdelman, Timothy, Department of Biogeochemistry, Max Planck Institute for Marine Microbiology, Fahrenheitstrasse 1, W-28359 Bremen, Germany; Fossing, Henrik, Department of Biogeochemistry, Max Planck Institute for Marine Microbiology, Fahrenheitstrasse 1, W-28359 Bremen, Germany / http://dx.doi.org/10.1021/bk-1995-0612.ch003

Organic Geochemistry of Sulfur-Rich Surface Sediments of Meromictic Lake Cadagno, Swiss Alps / Putschew, Anke; Scholz-Böttcher, Barbara M.; Rullkötter, Jürgen / http://dx.doi.org/10.1021/bk-1995-0612.ch004

Influence of Sulphur Cross-linking on the Molecular-Size Distribution of Sulphur-Rich Macromolecules in Bitumen / Schouten, Stefan, Division of Marine Biogeochemistry, Netherlands Institute for Sea Research (NIOZ), P.O. Box 59, 1790 AB Den Burg, Texel, Netherlands; Eglinton, Timothy I., Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, MA 02543; Sinninghe Damsté, Jaap S., Division of Marine Biogeochemistry, Netherlands Institute for Sea Research (NIOZ), P.O. Box 59, 1790 AB Den Burg, Texel, Netherlands; de Leeuw, Jan W., Division of Marine Biogeochemistry, Netherlands Institute for Sea Research (NIOZ), P.O. Box 59, 1790 AB Den Burg, Texel, Netherlands / http://dx.doi.org/10.1021/bk-1995-0612.ch005

Alkanoic Subunits in Sulfur-Rich Geomacromolecules: Information from Stepwise Chemical Degradation and Compound-Specific Isotopic Analysis / Hefter, J.; Hauke, V.; Richnow, H. H.; Michaelis, W. / http://dx.doi.org/10.1021/bk-1995-0612.ch006

Proposed Thermal Pathways for Sulfur Transformations in Organic Macromolecules: Laboratory Simulation Experiments / Krein, Eitan B.; Aizenshtat, Zeev / http://dx.doi.org/10.1021/bk-1995-0612.ch007

Transformations in Organic Sulfur Speciation During Maturation of Monterey Shale: Constraints from Laboratory Experiments / Nelson, Bryan C., Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, MA 02543; Eglinton, Timothy I., Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, MA 02543; Seewald, Jeffrey S., Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, MA 02543; Vairavamurthy, Murthy A., Department of Applied Science, Geochemistry Program, Applied Physical Sciences Division, Brookhaven National Laboratory, Upton, NY 11973; Miknis, Francis P., Western Research Institute, Laramie, WY 82071 / http://dx.doi.org/10.1021/bk-1995-0612.ch008

Chemistry of Iron Sulfides in Sedimentary Environments / Rickard, David, Department of Earth Sciences, University of Wales, Cardiff CF1 3YE, Wales, United Kingdom; Schoonen, Martin A. A., Department of Earth and Space Sciences, State University of New York, Stony Brook, NY 11794-2100; Luther, G. W., College of Marine Studies, University of Delaware, Lewes, DE 19958 / http://dx.doi.org/10.1021/bk-1995-0612.ch009

Reactions Forming Pyrite from Precipitated Amorphous Ferrous Sulfide / Furukawa, Yoko, Current address: Naval Research Laboratory, Code 7431, Stennis Space Center, MS 39529; Barnes, H. L. / http://dx.doi.org/10.1021/bk-1995-0612.ch010

Laboratory Simulation of Pyrite Formation in Anoxic Sediments / Wang, Qiwei; Morse, John W. / http://dx.doi.org/10.1021/bk-1995-0612.ch011

Environmental Controls on Iron Sulfide Mineral Formation in a Coastal Plain Estuary / Cornwell, Jeffrey C.; Sampou, Peter A. / http://dx.doi.org/10.1021/bk-1995-0612.ch012

Digestion Procedures for Determining Reduced Sulfur Species in Bacterial Cultures and in Ancient and Recent Sediments / Allen, R. E.; Parkes, R. J. / http://dx.doi.org/10.1021/bk-1995-0612.ch013

Oxidation of Hydrogen Sulfide by Mn(IV) and Fe(III) (Hydr)Oxides in Seawater / Yao, Wensheng; Millero, Frank H. / http://dx.doi.org/10.1021/bk-1995-0612.ch014

Characterization of a Transient +2 Sulfur Oxidation State Intermediate from the Oxidation of Aqueous Sulfide / Vairavamurthy, Murthy A.; Zhou, Weiqing / http://dx.doi.org/10.1021/bk-1995-0612.ch015

Temporal Relationship of Thiols to Inorganic Sulfur Compounds in Anoxic Chesapeake Bay Sediment Porewater / MacCrehan, William; Shea, Damian / http://dx.doi.org/10.1021/bk-1995-0612.ch016

The Distribution of Free Organic Sulfur Compounds in Sediments from the Nördlinger Ries, Southern Germany / Barakat, Assem O., Department of Chemistry, Faculty of Science, Alexandria University, P.O. Box 426, 21321 Alexandria, Egypt; Rullkötter, Jürgen, Institute of Chemistry and Biology of the Marine Environment (ICBM), Carl von Ossietzky University of Oldenburg, P.O. Box 2503, D-26111 Oldenburg, Germany / http://dx.doi.org/10.1021/bk-1995-0612.ch017

Sulfate Incorporation into Sedimentary Carbonates / Staudt, Wilfried J.; Schoonen, Martin A. A. / http://dx.doi.org/10.1021/bk-1995-0612.ch018

35S-Radiolabeling To Probe Biogeochemical Cycling of Sulfur / Fossing, Henrik / http://dx.doi.org/10.1021/bk-1995-0612.ch019

Microbial Assimilation and Dissimilation of Sulfonate Sulfur / Seitz, A. P.; Leadbetter, E. R.

/ http://dx.doi.org/10.1021/bk-1995-0612.ch020

Isotopic Evidence for the Origin of Organic Sulfur and Elemental Sulfur in Marine Sediments / Anderson, Thomas F., Department of Geology, University of Illinois, Urbana, IL 61801; Pratt, Lisa M., Biogeochemical Laboratories and Department of Geological Sciences, Indiana University, Bloomington, IN 47405 / http://dx.doi.org/10.1021/bk-1995-0612.ch021

Stable Sulfur Isotopic Compositions of Chromium-Reducible Sulfur in Lake Sediments / Fry, Brian, Current address: Department of Biology, Florida International University, University Park, FL 33199; Giblin, Anne; Dornblaser, Mark; Peterson, Bruce / http://dx.doi.org/10.1021/bk-1995-0612.ch022

Kinetic Controls on Thermochemical Sulfate Reduction as a Source of Sedimentary H2S / Goldhaber, Martin B., U.S. Geological Survey, Mail Stop 973, Denver Federal Center, Denver, CO 80225; Orr, Wilson L., Earth and Energy Science Advisors, P.O. Box 3729, Dallas, TX 75208 / http://dx.doi.org/10.1021/bk-1995-0612.ch023

Controls on the Origin and Distribution of Elemental Sulfur, H2S, and CO2 in Paleozoic Hydrocarbon Reservoirs in Western Canada / Hutcheon, Ian, Department of Geology and Geophysics, University of Calgary, Calgary, Alberta T2N 1N4, Canada; Krouse, H. Roy, Department of Physics and Astronomy, University of Calgary, Calgary, Alberta T2N 1N4, Canada; Abercrombie, Hugh J., The Institute of Sedimentary and Petroleum Geology, 3303 33rd Street, Northwest, Calgary, Alberta T2L 2A7, Canada / http://dx.doi.org/10.1021/bk-1995-0612.ch024

Devonian Nisku Sour Gas Play, Canada: A Unique Natural Laboratory for Study of Thermochemical Sulfate Reduction / Machel, H. G., Department of Geology, University of Alberta, Edmonton, Alberta T6G 2E3, Canada; Krouse, H. Roy, Department of Physics and Astronomy, University of Calgary, Calgary, Alberta T2N 1N4, Canada; Riciputi, L. R., Chemical and Analytical Science Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831; Cole, D. R., Chemical and Analytical Science Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 / http://dx.doi.org/10.1021/bk-1995-0612.ch025

Macromolecules > Analysis > Research.

Isotopes > Analysis.

Laboratories > Experiments > Simulation methods.

Shale > Analysis > Research.

Pyrites > Analysis > Research.

Ferrous sulfate > Research.

Pyrites > Formation.

Iron compounds > Formation.

Estuaries > Research.

Bacteriology > Cultures and culture media.

Hydrogen sulfide > Oxidation.

Seawater > Analysis.

Sulfur > Oxidation.

Sulfides > Oxidation.

Sulfur compounds > Chesapeake Bay (Md. and Va.)

Sulfur compounds > Germany, Southern.

Carbonates > Research.

Sulfonates > Analysis.

Marine sediments > Analysis.

Lake sediments > Analysis.

Hydrocarbon reservoirs > Canada.

Natural gas > Canada.

Geologic Sediments.

Sulfur - chemistry.

Hydrocarbons - chemistry.

Alkanes - analysis.

Sulfur Compounds - analysis.

Iron - chemistry.

Sulfides - chemistry.

Ferrous Compounds - chemistry.

Estuaries.

Microbial Phenomena.

Hydrogen Sulfide - chemistry.

Manganese Compounds - chemistry.

Ferric Compounds - chemistry.

Seawater - chemistry.

Sulfur Oxides - chemistry.

Carbonates - chemistry.

American Chemical Society. Division of Geochemistry, sponsoring body.

American Chemical Society. Meeting (208th : 1994 : Washington, D.C.)