Papers presented at a symposium held at the 218th National Meeting of the American Chemical Society in New Orleans from August 22-26, 1999.

Distributed in print by Oxford University Press.

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ACS symposium series, 778

The Environmental Management Science Program: One Facet of a Balanced Solution-Based Investment Strategy / Boyd, Gerald, Office of Science and Technology, Office of Environmental Management, Department of Energy, 1000 Independence Avenue, Washington, DC 20585; Gilbertson, Mark, Office of Basic and Applied Research, Office of Science and Technology, Office of Environmental Management, Department of Energy, 1000 Independence Avenue, Washington, DC 20585; Hirsch, Roland, Medical Sciences Division, Office of Biological and Environmental Research, Office of Science, Department of Energy, Germantown, MD 20585; Gritzke, Arnold, Office of Basic and Applied Research, Office of Science and Technology, Office of Environmental Management, Department of Energy, 1000 Independence Avenue, Washington, DC 20585 / http://dx.doi.org/10.1021/bk-2001-0778.ch001

Challenges and Scientific Issues for the Department of Energy Weapons Complex Cleanup: High-Level Waste and Spent Nuclear Fuel / Kuhn, William L. / http://dx.doi.org/10.1021/bk-2001-0778.ch002

The Subsurface Contaminants Focus Area: Innovative Technology Development for Environmental Remediation / Price, Van / http://dx.doi.org/10.1021/bk-2001-0778.ch003

Actinide Behavior in Neutral Media / Choppin, G. R. / http://dx.doi.org/10.1021/bk-2001-0778.ch004

The Aqueous Complexation of Eu(III) with Organic Chelates at High-Base Concentration: Molecular and Thermodynamic Modeling Results / Felmy, Andrew R.; Wang, Zheming; Dixon, David A.; Joly, Alan G.; Rustad, James R.; Mason, Marvin J. / http://dx.doi.org/10.1021/bk-2001-0778.ch005

Eu3+ and UO2 2+ Surface Complexes on SiO2 and TiO2: Models for Testing Mediated Electrochemical Methods for the Treatment of Actinide Processing Residues / Diaz, Tammy A., Current address: N. M. Highlands University, Las Vegas, NM 87701; Ehler, Deborah S.; Burns, Carol J.; Morris, Davis E. / http://dx.doi.org/10.1021/bk-2001-0778.ch006

Phase Chemistry and Radionuclide Retention of High-Level Radioactive Waste Tank Sludges / Krumhansl, J. L., Sandia National Laboratories, Albuquerque, NM 87185-0750; Brady, P. V., Sandia National Laboratories, Albuquerque, NM 87185-0750; Zhang, P. C., Sandia National Laboratories, Albuquerque, NM 87185-0750; Arthur, S., Sandia National Laboratories, Albuquerque, NM 87185-0750; Hutcherson, S. K., Sandia National Laboratories, Albuquerque, NM 87185-0750; Liu, J., Pacific Northwest National Laboratory, 3350 Q Street, Richland, WA 99352; Qian, M., Pacific Northwest National Laboratory, 3350 Q Street, Richland, WA 99352; Anderson, H. L., Sandia National Laboratories, Albuquerque, NM 87185-0750 / http://dx.doi.org/10.1021/bk-2001-0778.ch007

Use of Cage-Functionalized Macrocycles and Fluorinated Alcohols in the Liquid-Liquid Extraction of NaOH and Other Sodium Salts: Strategies Toward Waste-Volume Reduction / Moyer, Bruce A., Chemical and Analytical Sciences Division, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, TN 37830-6119; Bonnesen, Peter V., Chemical and Analytical Sciences Division, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, TN 37830-6119; Chambliss, C. Kevin, Chemical and Analytical Sciences Division, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, TN 37830-6119; Haverlock, Tamara J., Chemical and Analytical Sciences Division, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, TN 37830-6119; Marchand, Alan P., Department of Chemistry, University of North Texas, NT Station, Avenue C at Sycamore Street, Denton, TX 76203-5070; Chong, Hyun-Soon, Department of Chemistry, University of North Texas, NT Station, Avenue C at Sycamore Street, Denton, TX 76203-5070; McKim, Artie S., Department of Chemistry, University of North Texas, NT Station, Avenue C at Sycamore Street, Denton, TX 76203-5070; Krishnudu, Kasireddy, Department of Chemistry, University of North Texas, NT Station, Avenue C at Sycamore Street, Denton, TX 76203-5070; Ravikumar, K. S., Department of Chemistry, University of North Texas, NT Station, Avenue C at Sycamore Street, Denton, TX 76203-5070; Kumar, V. Satish, Department of Chemistry, University of North Texas, NT Station, Avenue C at Sycamore Street, Denton, TX 76203-5070; Takhi, Mohamed, Department of Chemistry, University of North Texas, NT Station, Avenue C at Sycamore Street, Denton, TX 76203-5070 / http://dx.doi.org/10.1021/bk-2001-0778.ch008

The Use of Synthetic Inorganic Ion Exchangers in the Removal of Cesium and Strontium Ions from Nuclear Waste Solutions / Sylvester, Paul; Clearfield, Abraham / http://dx.doi.org/10.1021/bk-2001-0778.ch009

Stepwise Assembly of Surface Imprint Sites on MCM-41 for Selective Metal Ion Separations / Burleigh, M. C., Chemical Technology, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, TN 37831, Chemical and Analytical Sciences Divisions, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, TN 37831; Dai, Sheng, Chemical Technology, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, TN 37831; Hagaman, E. W., Chemical and Analytical Sciences Divisions, Oak Ridge National Laboratory, Bethel Valley Road, Oak Ridge, TN 37831; Barnes, C. E., Department of Chemistry, University of Tennessee, Knoxville, TN 37996; Xue, Z. L., Department of Chemistry, University of Tennessee, Knoxville, TN 37996 / http://dx.doi.org/10.1021/bk-2001-0778.ch010

Extraction of Metals from Soils Using Fluoro-Supported Ligands in CO2 / Apodaca, D. L., Los Alamos National Laboratory, MS J514, Los Alamos, NM 87545; Birnbaum, E. R., Los Alamos National Laboratory, MS E518, Los Alamos, NM 87545; McCleskey, T. M., Los Alamos National Laboratory, MS J514, Los Alamos, NM 87545; Young, T. M., Department of Civil and Environmental Engineering, University of California at Davis, One Shields Avenue, 150 Everson Hall, Davis, CA 95616 / http://dx.doi.org/10.1021/bk-2001-0778.ch011

Synthesis, Characterization and Ion Exchange of Novel Sodium Niobate Phases / Nenoff, T. M., Sandia National Laboratory, Org. 1845, M.S. 0710, Albuquerque, NM 87185-0710; Nyman, M., Sandia National Laboratory, Org. 1845, M.S. 0710, Albuquerque, NM 87185-0710; Su, Y., Pacific Northwest Laboratories, MSIN K8-93, Battelle Boulevard, Richland, WA 99352; Balmer, M. L., Pacific Northwest Laboratories, MSIN K8-93, Battelle Boulevard, Richland, WA 99352; Navrotsky, A.; Xu, H. / http://dx.doi.org/10.1021/bk-2001-0778.ch012

Oxidation of Selected Polycyclic Aromatic Hydrocarbons by the Fenton's Reagent: Effect of Major Factors Including Organic Solvent / Qiang, Z.; Chang, J. H.; Huang, C. P.; Cha, D. / http://dx.doi.org/10.1021/bk-2001-0778.ch013

Interaction of Water and Aqueous Chromium Ions with Iron Oxide Surfaces / Brown, G. E., Surface and Aqueous Geochemistry Group, Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305-2115, Stanford Synchrotron Radiation Laboratory, SLAC, Stanford, CA 94309; Chambers, S. A., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 908 Battelle Boulevard, Richland, WA 99352; Amonette, J. E., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 908 Battelle Boulevard, Richland, WA 99352; Rustad, J. R., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 908 Battelle Boulevard, Richland, WA 99352; Kendelewicz, T., Surface and Aqueous Geochemistry Group, Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305-2115; Liu, P., Surface and Aqueous Geochemistry Group, Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305-2115; Doyle, C. S., Surface and Aqueous Geochemistry Group, Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305-2115; Grolimund, D., Surface and Aqueous Geochemistry Group, Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305-2115; Foster-Mills, N. S., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 908 Battelle Boulevard, Richland, WA 99352; Joyce, S. A., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 908 Battelle Boulevard, Richland, WA 99352; Thevuthasan, S., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 908 Battelle Boulevard, Richland, WA 99352 / http://dx.doi.org/10.1021/bk-2001-0778.ch014

Electroosmotic Flow Rate: A Semiempirical Approach / Chang, J. H.; Qiang, Z.; Huang, C. P.; Cha, D. / http://dx.doi.org/10.1021/bk-2001-0778.ch015

Reductive Dechlorination of Trichloroethylene and Carbon Tetrachloride at Iron Oxides and Basalt Minerals / Ingram, Jani C., Idaho National Engineering and Environmental Laboratory, Idaho Falls, ID 83415-2208; Cortez, Marnie M., Idaho National Engineering and Environmental Laboratory, Idaho Falls, ID 83415-2208; Bates, David L., Department of Geology, Idaho State University, Pocatello, ID 83209; McCurry, Michael O., Department of Geology, Idaho State University, Pocatello, ID 83209 / http://dx.doi.org/10.1021/bk-2001-0778.ch016

Radiation-Induced Processes in Aqueous Suspensions of Nanoparticles and Nanoscale Water Films: Relevance to H2 Production in Mixed Waste and Spent Nuclear Fuel / Orlando, Thom M., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, 908 Battelle Boulevard, Richland, WA 99352; Meisel, Dan, Radiaton Laboratory and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 / http://dx.doi.org/10.1021/bk-2001-0778.ch017

Thermochemical Kinetic Analysis of Mechanism for Thermal Oxidation of Organic Complexants in High-Level Wastes / Camaioni, Donald M.; Autrey, Tom / http://dx.doi.org/10.1021/bk-2001-0778.ch018

Kinetics of Conversion of High-Level Waste to Glass / Izak, P.; Hrma, P.; Schweiger, M. J. / http://dx.doi.org/10.1021/bk-2001-0778.ch019

The Nature of the Self-Luminescence Observed from Borosilicate Glass Doped with Es / Assefa, Zerihun; Haire, Richard G. / http://dx.doi.org/10.1021/bk-2001-0778.ch020

Radiation and Chemistry in Nuclear Waste: The NOx System and Organic Aging / Meisel, Dan, Notre Dame Radiation Laboratory, and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556; Camaioni, Donald M., Energy and Health Sciences Division, Pacific Northwest National Laboratory, Richland, WA 99352; Orlando, Thom M., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352 / http://dx.doi.org/10.1021/bk-2001-0778.ch021

Novel Spectroelectrochemical Sensor for Ferrocyanide in Hanford Waste Simulant / Maizels, Mila, Chemistry Department, University of Cincinnati, Cincinnati, OH 45221-0172; Stegemiller, Michael, Chemistry Department, University of Cincinnati, Cincinnati, OH 45221-0172; Ross, Susan, Chemistry Department, University of Cincinnati, Cincinnati, OH 45221-0172; Slaterbeck, Andrew, Chemistry Department, University of Cincinnati, Cincinnati, OH 45221-0172; Shi, Yining, Chemistry Department, University of Cincinnati, Cincinnati, OH 45221-0172; Ridgway, Thomas H., Chemistry Department, University of Cincinnati, Cincinnati, OH 45221-0172; Heineman, William R., Chemistry Department, University of Cincinnati, Cincinnati, OH 45221-0172; Seliskar, Carl J., Chemistry Department, University of Cincinnati, Cincinnati, OH 45221-0172; Bryan, Samuel A., Pacific Northwest National Laboratory, 908 Battelle Boulevard, Richland, WA 99352 / http://dx.doi.org/10.1021/bk-2001-0778.ch022

Refinement of Immunochemical Methods for Environmental Analysis of Polycyclic Aromatic Hydrocarbons / Li, Qing X., Department of Molecular Biosciences and Biosystems Engineering, University of Hawaii at Manoa, Honolulu, HI 96822; Karu, Alexander E., Department of Nutritional Sciences, University of California, Berkeley, CA 94720; Li, Kai, Department of Molecular Biosciences and Biosystems Engineering, University of Hawaii at Manoa, Honolulu, HI 96822; Thomas, Steven, Department of Molecular Biosciences and Biosystems Engineering, University of Hawaii at Manoa, Honolulu, HI 96822 / http://dx.doi.org/10.1021/bk-2001-0778.ch023

Architecture of Antibody Binding Sites for Polynuclear Aromatic Hydrocarbons / Pellequer, Jean-Luc, Department of Molecular Biology, The Scripps Research Institute, La Jolla, CA 92037; Chen, Shu-wen W., Department of Molecular Biology, The Scripps Research Institute, La Jolla, CA 92037; Feeney, Ann J., Department of Immunology, The Scripps Research Institute, La Jolla, CA 92037; Zhao, Bitao, Department of Nutritional Science, University of California, Berkeley, CA 94720; Kao, Hui-I, Department of Nutritional Science, University of California, Berkeley, CA 94720; Karu, Alexander E., Department of Nutritional Science, University of California, Berkeley, CA 94720; Li, Kai, Department of Environmental Biochemistry, University of Hawaii at Manoa, Honolulu, HI 96822; Li, Qing X., Department of Environmental Biochemistry, University of Hawaii at Manoa, Honolulu, HI 96822; Roberts, Victoria A., Department of Molecular Biology, The Scripps Research Institute, La Jolla, CA 92037 / http://dx.doi.org/10.1021/bk-2001-0778.ch024

Genotypic Influence on Metal Ion Mobilization and Sequestration via Metal Ion Ligand Production by Wheat / Fan, Teresa W.-M., Department of Land, Air and Water Resources, University of California, One Shields Avenue, Davis, CA 95616-8627; Baraud, Fabienne, Department of Land, Air and Water Resources, University of California, One Shields Avenue, Davis, CA 95616-8627; Higashi, Richard M., Department of Crocker Nuclear Laboratory, University of California, One Shields Avenue, Davis, CA 95616-8627 / http://dx.doi.org/10.1021/bk-2001-0778.ch025

Radioactive waste sites > Cleanup > United States.

Spent reactor fuels > Management.

Actinide elements > Reactivity.

Europium > Isotopes > Reactivity > Models.

Actinide elements > Processing > By-products > Management > Methodology.

Radioisotopes > Decay.

Macrocyclic compounds > Industrial applications.

Radioactive wastes > Separation.

Metal ions > Separation.

Soils > Separation.

Niobates > Properties.

Polycyclic aromatic hydrocarbons > Oxidation.

Ferric oxide > Surfaces > Reactivity.

Electro-osmosis > Diffusion rate.

Hydrogen > Formation.

Organic compounds > Oxidation > Thermal properties.

Radioactive wastes > Processing > Mechamism of action.

Nitrous oxide > Industrial applications.

Radioactive wastes > Spectra.

Ferrocyanides > Spectra.

Polycyclic aromatic hydrocarbons > Analysis > Environmental aspects.

Polycyclic aromatic hydrocarbons > Structure.

Metal ions > Mechanism of action.

Radioactive Waste.

Environmental Restoration and Remediation.

Hazardous Waste Sites.

Europium.

Radioisotopes.

Macrocyclic Compounds.

Waste Management.

Soil.

Polycyclic Aromatic Hydrocarbons.

Polycyclic Aromatic Hydrocarbons - analysis.

Ferric Compounds.

Hydrogen.

Chemistry, Organic.

Nitrous Oxide.

Luminescence.

Ferrocyanides.

Binding Sites.

Waste Disposal, Fluid.

American Chemical Society. Division of Nuclear Chemistry and Technology, sponsoring body.

American Chemical Society. Division of Industrial and Engineering Chemistry, sponsoring body.

American Chemical Society. Division of Analytical Chemistry, sponsoring body.

American Chemical Society. Division of Physical Chemistry, sponsoring body.

American Chemical Society. Division of Environmental Chemistry, sponsoring body.

American Chemical Society. Meeting (218th : 1999 : New Orleans, Louisiana)