Developed from a symposium sponsored by the Division of Polymer Chemistry, Inc., at the 221st National Meeting of the American Chemical Society, San Diego, California, April 1-5, 2001.

Distributed in print by Oxford University Press.

Description based on publisher-supplied information and home-page.

Original

Online version

Original

ACS symposium series, 838

Silicones and Silicone-Modified Materials: A Concise Overview / Clarson, Stephen J. / http://dx.doi.org/10.1021/bk-2003-0838.ch001

Controlled Synthesis of All Siloxane-Functionalized Architectures by Ring-Opening Polymerization / Chojnowski, J.; Cypryk, M.; Fortuniak, W.; Kaźmierski, K.; Rózga-Wijas, K.; Ścibiorek, M. / http://dx.doi.org/10.1021/bk-2003-0838.ch002

Novel Methods of Catalyzing Polysiloxane Syntheses / Embery, C. J., Polymer Science Group, Ian Wark Research Institute, University of South Australia, Mawson Lakes, SA 5095, Australia; Matisons, J. G., Polymer Science Group, Ian Wark Research Institute, University of South Australia, Mawson Lakes, SA 5095, Australia, Current address: School of Chemistry, Physic and Earth Sciences, The Flinders University of South Australia, G.P. Office 2001, Adelaide, South Australia 5001, Australia; Clarke, S. R., Polymer Science Group, Ian Wark Research Institute, University of South Australia, Mawson Lakes, SA 5095, Australia, Current address: School of Chemistry, Physic and Earth Sciences, The Flinders University of South Australia, G.P. Office 2001, Adelaide, South Australia 5001, Australia / http://dx.doi.org/10.1021/bk-2003-0838.ch003

Anionic Ring-Opening Polymerization of cis-2,4,6-Trimethyl-2',4',6'-triphenyl Cyclotrisiloxane (cis-P3) in Cyclohexane / Ahn, H. W.; Clarson, S. J. / http://dx.doi.org/10.1021/bk-2003-0838.ch004

Ru-Catalyzed Hydrosilylation Polymerization: An Overview of RuH2(CO)(PPh3)3-Catalyzed Hydrosilylation Copolymerizations of α,ω-Diketones with α,ω-Dihydrido-oligodimethylsiloxanes and Polymerizations of ω-Dimethylsilyloxy Ketones / Mabry, Joseph M.; Runyon, Matthew K.; Paulasaari, Jyri K.; Weber, William P., Corresponding author: email: wpweber@usc.edu / http://dx.doi.org/10.1021/bk-2003-0838.ch005

Synthesis and Characterization of Siloxane-Containing Polymers Obtained by Dehydrocoupling Polymerization / Kawakami, Yusuke; Imae, Ichiro / http://dx.doi.org/10.1021/bk-2003-0838.ch006

Synthesis of Linear Copolysiloxanes with Regular Microstructures and Synthesis of Soluble Polysiloxanes with Trifunctional RSiO3/2 (T) or Tetrafunctional SiO4/2 (Q) Units / Weber, William P., K. B. and D. P. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, Los Angles, CA 90089-1661, Corresponding author: email: wpweber@usc.edu; Paulasaari, Jyri Kalevi, K. B. and D. P. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, Los Angles, CA 90089-1661; Cai, Guoping, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, China / http://dx.doi.org/10.1021/bk-2003-0838.ch007

Polysiloxanes in Compressed Carbon Dioxide / Folk, Sarah L., Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599; DeSimone, Joseph M., Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599, Department of Chemical Engineering, North Carolina State University, Raleigh, NC 27695 / http://dx.doi.org/10.1021/bk-2003-0838.ch008

Neutron Scattering Studies of Cyclic and Linear Poly(dimethylsiloxanes) / Dagger, A. C., Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom, Current address: Smith and Nephew Group Research Center, York Science Park, Heslington, York YO10 5DF, United Kingdom; Arrighi, V., Chemistry Department, Heriot-Watt University, Riccarton, Edinburgh EH14 4AS, United Kingdom; Gagliardi, S., Chemistry Department, Heriot-Watt University, Riccarton, Edinburgh EH14 4AS, United Kingdom; Shenton, M. J., Polymer Research Centre, School of Physics and Chemistry, University of Surrey, Guildford, Surrey GU2 7XH, United Kingdom; Clarson, S. J., Polymer Research Center, College of Engineering, University of Cincinnati, Cincinnati, OH 45221-0012; Semlyen, J. A., Department of Chemistry, University of York, Heslington, York YO10 5DD, United Kingdom, Tony Semlyen left us in this world shortly before the oral presentation of this work that was given in San Diego by Tony Dagger. . / http://dx.doi.org/10.1021/bk-2003-0838.ch009

Photoexcitation and Photoemission Spectra of Phenyl-Substituted Cyclosiloxanes / Backer, Michael W., Dow Corning Limited, New Ventures R & D, Chemical Synthesis Research Group, Cardiff Road, Barry, South Glamorgan CF63 2YL, United Kingdom; Pernisz, Udo C., Dow Corning Corporation, New Ventures R & D, Physics Research Group, 2200 West Salzburg Road, Midland, MI 48686 / http://dx.doi.org/10.1021/bk-2003-0838.ch010

Measuring the Size and Shape of Silicones: The Utilization of Chemometrics and Spectroscopy / Shenton, Martyn J., Polymer Research Centre, School of Physics and Chemistry, University of Surrey, Guildford, Surrey GU2 7XH, United Kingdom, Current address: AG Fluoropolymers, P.O. Box 4, Thornton, Lancashire FY5 4QD, United Kingdom; Herman, Henryk, Polymer Research Centre, School of Physics and Chemistry, University of Surrey, Guildford, Surrey GU2 7XH, United Kingdom; Dagger, Anthony C., Smith and Nephew GRC, York Science Park, Heslington, York YO10 5DF, United Kingdom / http://dx.doi.org/10.1021/bk-2003-0838.ch011

Thermally Stable Siloxane Polymers for Gas Chromatography / Day, G. M.; Hibberd, A. I.; Habsuda, J.; Sharp, G. J. / http://dx.doi.org/10.1021/bk-2003-0838.ch012

The Effect of Thermal Aging on the Non-Network Species in Room Temperature Vulcanized Polysiloxane Rubbers / Patel, Mogon; Skinner, Anthony R. / http://dx.doi.org/10.1021/bk-2003-0838.ch013

Prediction of the Elastomeric Modulus of Poly(dimethylsiloxane) Networks Formed by Endlinking / Stepto, R. F. T.; Cail, J. I.; Taylor, D. J. R. / http://dx.doi.org/10.1021/bk-2003-0838.ch014

Structure-Property Relationships for Poly(dimethylsiloxane) Networks In Situ Filled Using Titanium 2-Ethylhexoxide and Zirconium n-Butoxide / Murugesan, S., Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221; Mark, J. E., Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221; Beaucage, G., Department of Materials Science, University of Cincinnati, Cincinnati, OH 45221 / http://dx.doi.org/10.1021/bk-2003-0838.ch015

Modulus Reduction Mechanism of Trimethylsiloxy Silicates in a Polyorganosiloxane / Schmidt, Randall G.; Badour, Linda R.; Gordon, Glenn V. / http://dx.doi.org/10.1021/bk-2003-0838.ch016

NMR Spin Relaxation, Self-Diffusion and Viscosity Studies of Poly(dimethylsiloxane)s Blended with Silicate Nanoparticles / Roberts, Claire, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, United Kingdom; Cosgrove, Terence, School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, United Kingdom; Schmidt, Randall G., School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, United Kingdom; Gordon, Glenn V., Dow Corning Corporation, 2200 West Salzburg Road, Midland, MI 48686-0994; Goodwin, Andrew J., Dow Corning Ltd., Cardiff Road, Barry, S. Glamorgan CF63 2YL, United Kingdom; Kretschmer, Axel, Dow Corning Ltd., Cardiff Road, Barry, S. Glamorgan CF63 2YL, United Kingdom / http://dx.doi.org/10.1021/bk-2003-0838.ch017

Investigating the Energetics of Bioadhesion on Microengineered Siloxane Elastomers: Characterizing the Topography, Mechanical Properties, and Surface Energy and Their Effect on Cell Contact Guidance / Feinberg, Adam W., Biomedical Engineering Program, University of Florida, Gainesville, FL 32611, Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611; Gibson, Amy L., Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611; Wilkerson, Wade R., Biomedical Engineering Program, University of Florida, Gainesville, FL 32611, Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611; Seegert, Charles A., Biomedical Engineering Program, University of Florida, Gainesville, FL 32611, Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611; Wilson, Leslie H., Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611; Zhao, Lee C., Biomedical Engineering Program, University of Florida, Gainesville, FL 32611, Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611; Baney, Ronald H., Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611; Callow, James A., University of Birmingham, School of Biosciences, Birmingham B15 2TT, United Kingdom; Callow, Maureen E., University of Birmingham, School of Biosciences, Birmingham B15 2TT, United Kingdom; Brennan, Anthony B., Biomedical Engineering Program, University of Florida, Gainesville, FL 32611, Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611 / http://dx.doi.org/10.1021/bk-2003-0838.ch018

Exploiting Favorable Silicone-Protein Interactions: Stabilization against Denaturation at Oil-Water Interfaces / Zelisko, Paul M.; Bartzoka, Vasiliki; Brook, Michael A. / http://dx.doi.org/10.1021/bk-2003-0838.ch019

Association of Siloxane Polymeric Surfactants in Aqueous Solution / Lin, Yining; Alexandridis, Paschalis / http://dx.doi.org/10.1021/bk-2003-0838.ch020

Poly(amidoamine organosilicon) Dendrimers and Their Derivatives of Higher Degree of Structural Complexity / Dvornic, Petar R.; Owen, Michael J. / http://dx.doi.org/10.1021/bk-2003-0838.ch021

Surfactant Properties of Poly(dimethylsiloxane)-Containing Block Copolymers from Living Radical Polymerization / Bes, Laurence, Department of Chemistry, University of Warwick, Coventry CV4 7AL, United Kingdom; Huan, Kim, Department of Chemistry, University of Warwick, Coventry CV4 7AL, United Kingdom; Haddleton, David M., Department of Chemistry, University of Warwick, Coventry CV4 7AL, United Kingdom; Khoshdel, Ezat, Unilever Research, Port Sunlight, Quarry Road East, Bebington, Wirral CH63 3JW, United Kingdom / http://dx.doi.org/10.1021/bk-2003-0838.ch022

Organic-Inorganic Hybrid Materials from Polysiloxanes and Polysilsesquioxanes Using Controlled/Living Radical Polymerization / Pyun, Jeffrey; Xia, Jianhui; Matyjaszewski, Krzysztof / http://dx.doi.org/10.1021/bk-2003-0838.ch023

Preparation and Properties of Silicone-Urea Copolymers Doped with Cobalt(II) Chloride / Yilgör, E.; Gördeslioğlu, M.; Dizman, B.; Yilgör, I. / http://dx.doi.org/10.1021/bk-2003-0838.ch024

Block and Graft Copolymers Containing Poly(dimethylsiloxane) and Poly(4-vinyl-pyridine) Segments by Free Radical Polymerization / Kim, Yongsin, Maurice Morton Institute of Polymer Science, The University of Akron, Akron, OH 44325-3909; Graiver, Daniel, Dow Corning Corporation, 2200 West Salzburg Road, Midland, MI 48686-0994; Decker, Gary T., Dow Corning Corporation, 2200 West Salzburg Road, Midland, MI 48686-0994; Hamilton, Fernando J., Maurice Morton Institute of Polymer Science, The University of Akron, Akron, OH 44325-3909; Harwood, H. James, Maurice Morton Institute of Polymer Science, The University of Akron, Akron, OH 44325-3909 / http://dx.doi.org/10.1021/bk-2003-0838.ch025

Poly(dimethylsiloxane)-graft-oligo(hexafluoropropeneoxide) Via Ring-Opening Polymerization / Buese, Mark A.; Gonzalez, Jose F.; Harbaugh, Curtis G.; Stearman, Garrett M.; Williams, Michael S. / http://dx.doi.org/10.1021/bk-2003-0838.ch026

Silicone Graft Copolymers with Acrylonitrile, Chloroprene, Styrene, Methylmethacrylate, and an Olefin / Fawcett, Allan H.; Foster, Andrew B.; Hania, Majid; Hohn, Marcia; Mazebedi, Judge L.; McCaffery, Gerry O.; Mullen, Eddie; Toner, Declan / http://dx.doi.org/10.1021/bk-2003-0838.ch027

Synthesis and Properties of Poly(butylene terephthalate)-Poly(dimethylsiloxane) Block Copolymers / Schiraldi, David A. / http://dx.doi.org/10.1021/bk-2003-0838.ch028

The Synthesis of Vinyloxyacetate-Siloxane Copolymer and Its Absorption onto E Glass Fibers / Ma, Rosalind P.; Le-Huy, Christopher; Britcher, Leanne G.; Matisons, Janis G. / http://dx.doi.org/10.1021/bk-2003-0838.ch029

Silicification and Biosilicification: Part 2. Silicification at pH 7 in the Presence of a Cationically Charged Polymer in Solution and Immobilized on Substrates / Patwardhan, Siddharth V., Department of Materials Science and Engineering, University of Cincinnati, Cincinnati, OH 45221-0012; Durstock, Michael F., Air Force Research Laboratory, Wright-Patterson Air Force Base, Dayton, OH 45433; Clarson, Stephen J., Department of Materials Science and Engineering, University of Cincinnati, Cincinnati, OH 45221-0012 / http://dx.doi.org/10.1021/bk-2003-0838.ch030

Diffusion-Controlled Titanate-Catalyzed Condensation of Alkoxysilanes in Nonpolar Solvents / Zhou, Xiaobing; Hu, Sanlin; Shephard, Nick E.; Ahn, Dongchan / http://dx.doi.org/10.1021/bk-2003-0838.ch031

Siloxanes > Synthesis.

Silicones > Technological innovations.

Silicones > Synthesis.

Copolymers > Synthesis.

Gases, Compressed > Composition.

Polydimethylsiloxane > Molecular aspects > Analysis.

Photoemission > Spectra.

Silicones > Structure > Measurement > Methodology.

Gas chromatography > Materials.

Rubber, Artificial > Analysis.

Polydimethylsiloxane > Structure-property relationships.

Polydimethylsiloxane > Analysis.

Elastomers > Mechanical properties.

Proteins > Denaturation.

Dendrimers > Derivatives > Structure.

Polydimethylsiloxane > Surfaces > Properties.

Silicones > Properties.

Copolymers > Modification > Properties.

Block copolymers > Analysis.

Graft copolymers > Analysis.

Polybutenes > Properties.

Vinyl polymers > Synthesis > Absorption and adsorption.

Alkoxysilanes > Diffusion rate.

Silicones.

Siloxanes.

Cyclohexanes.

Photoelectron Spectroscopy.

Chromatography, Gas.

Elastomers.

Surface-Active Agents.

Polymers.

Dendrimers.

Scattering, Small Angle.

Magnetic Resonance Spectroscopy.

Polymerization.

American Chemical Society. Division of Polymer Chemistry, sponsoring body.

American Chemical Society. Meeting (221st : 2001 : San Diego, California)