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Online version

ACS symposium series, 1071

Introduction to Aquatic Redox Chemistry / Grundl, Timothy J., Geosciences Department and School of Freshwater Sciences, University of Wisconsin-Milwaukee, Milwaukee, WI 53201; Haderlein, Stefan, Center for Applied Geosciences, Eberhard-Karls Universität Tübingen, D-72076, Tübingen; Nurmi, James T., Division of Environmental and Biomolecular Systems, Oregon Health & Science University, Beaverton, OR 97006; Tratnyek, Paul G., Division of Environmental and Biomolecular Systems, Oregon Health & Science University, Beaverton, OR 97006 / http://dx.doi.org/10.1021/bk-2011-1071.ch001

Thermodynamic Redox Calculations for One and Two Electron Transfer Steps: Implications for Halide Oxidation and Halogen Environmental Cycling / Luther, George W. / http://dx.doi.org/10.1021/bk-2011-1071.ch002

One-Electron Reduction Potentials from Chemical Structure Theory Calculations / Bylaska, Eric J., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352; Salter-Blanc, Alexandra J., Division of Environmental and Biomolecular Systems, Oregon Health & Science University, 20000 NW Walker Road, Beaverton, OR 97006; Tratnyek, Paul G., Division of Environmental and Biomolecular Systems, Oregon Health & Science University, 20000 NW Walker Road, Beaverton, OR 97006 / http://dx.doi.org/10.1021/bk-2011-1071.ch003

Thermodynamic Control on Terminal Electron Transfer and Methanogenesis / Blodau, Christian / http://dx.doi.org/10.1021/bk-2011-1071.ch004

Redox Chemistry and Natural Organic Matter (NOM): Geochemists' Dream, Analytical Chemists' Nightmare / Macalady, Donald L., Department of Chemistry and Geochemistry, Colorado School of Mines, Golden, CO 80401; Walton-Day, Katherine, U.S. Geological Survey, Colorado Water Science Center, Denver Federal Center, Box 25046, MS 415, Denver, CO 80225 / http://dx.doi.org/10.1021/bk-2011-1071.ch005

Electron Shuttling by Natural Organic Matter: Twenty Years After / Sposito, Garrison / http://dx.doi.org/10.1021/bk-2011-1071.ch006

Electrochemistry of Natural Organic Matter / Nurmi, James T.; Tratnyek, Paul G. / http://dx.doi.org/10.1021/bk-2011-1071.ch007

Pathways Contributing to the Formation and Decay of Ferrous Iron in Sunlit Natural Waters / Garg, Shikha, School of Civil and Environmental Engineering, The University of New South Wales, Sydney, NSW 2052, Australia; Rose, Andrew L., School of Civil and Environmental Engineering, The University of New South Wales, Sydney, NSW 2052, Australia, Southern Cross GeoScience, Southern Cross University, Lismore NSW 2480, Australia; Waite, T. David, School of Civil and Environmental Engineering, The University of New South Wales, Sydney, NSW 2052, Australia / http://dx.doi.org/10.1021/bk-2011-1071.ch008

The Role of Iron Coordination in the Production of Reactive Oxidants from Ferrous Iron Oxidation by Oxygen and Hydrogen Peroxide / Remucal, Christina Keenan, Institute of Biogeochemistry and Pollutant Dynamics, ETH, Zürich, Switzerland; Sedlak, David L., Department of Civil and Environmental Engineering, University of California at Berkeley, Berkeley, California 94720 / http://dx.doi.org/10.1021/bk-2011-1071.ch009

TiO2 Photocatalysis for the Redox Conversion of Aquatic Pollutants / Lee, Jaesang, Water Environment Center, Environment Division, Korea Institute of Science and Technology (KIST), Hawolgok-dong, Seongbuk-gu, Seoul, Korea; Kim, Jungwon, School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 790-784, Korea; Choi, Wonyong, School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 790-784, Korea / http://dx.doi.org/10.1021/bk-2011-1071.ch010

Chlorine Based Oxidants for Water Purification and Disinfection / Korshin, Gregory V. / http://dx.doi.org/10.1021/bk-2011-1071.ch011

Remediation of Chemically-Contaminated Waters Using Sulfate Radical Reactions: Kinetic Studies / Mezyk, Stephen P., Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Blvd., Long Beach, CA 90840; Rickman, Kimberly A., Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Blvd., Long Beach, CA 90840; McKay, Garrett, Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Blvd., Long Beach, CA 90840; Hirsch, Charlotte M., Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Blvd., Long Beach, CA 90840; He, Xuexiang, School of Energy, Environment, Biological and Medical Engineering, University of Cincinnati, Cincinnati, OH 45221-0012; Dionysiou, Dionysios D., School of Energy, Environment, Biological and Medical Engineering, University of Cincinnati, Cincinnati, OH 45221-0012 / http://dx.doi.org/10.1021/bk-2011-1071.ch012

Voltammetry of Sulfide Nanoparticles and the FeS(aq) Problem / Helz, G. R., Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA; Ciglenečki, I., Center for Marine and Environmental Research, Ruđer Bošković Institute, Bijenička 54, 1000 Zagreb, Croatia; Krznarić, D., Center for Marine and Environmental Research, Ruđer Bošković Institute, Bijenička 54, 1000 Zagreb, Croatia; Bura-Nakić, E., Center for Marine and Environmental Research, Ruđer Bošković Institute, Bijenička 54, 1000 Zagreb, Croatia / http://dx.doi.org/10.1021/bk-2011-1071.ch013

Redox Reactivity of Organically Complexed Iron(II) Species with Aquatic Contaminants / Strathmann, Timothy J. / http://dx.doi.org/10.1021/bk-2011-1071.ch014

Fe2+ Sorption at the Fe Oxide-Water Interface: A Revised Conceptual Framework / Gorski, Christopher A., Environmental Chemistry, Eawag, Swiss Federal Institute of Aquatic Science and Technology, 8600 Duebendorf, Switzerland; Scherer, Michelle M., Civil and Environmental Engineering, University of Iowa, Iowa City, IA, 52242, USA / http://dx.doi.org/10.1021/bk-2011-1071.ch015

Redox Driven Stable Isotope Fractionation / Black, Jay R., Institute for Geophysics and Planetary Physics, University of California, Los Angeles, 595 Charles E. Young Drive East, Los Angeles, CA 90095; Crawford, Jeffrey A., Institute for Geophysics and Planetary Physics, University of California, Los Angeles, 595 Charles E. Young Drive East, Los Angeles, CA 90095; John, Seth, Department of Earth and Ocean Sciences, University of South Carolina, Columbia, SC 29208; Kavner, Abby, Institute for Geophysics and Planetary Physics, University of California, Los Angeles, 595 Charles E. Young Drive East, Los Angeles, CA 90095, Earth and Space Sciences, University of California, Los Angeles, 595 Charles E. Young Drive East, Los Angeles, CA 90095 / http://dx.doi.org/10.1021/bk-2011-1071.ch016

Redox Properties of Structural Fe in Smectite Clay Minerals / Neumann, Anke, Institute of Biogeochemistry and Pollutant Dynamics (IBP), Swiss Federal Institute of Technology (ETH) Zürich, Universitätsstr. 16, 8092 Zürich, Switzerland; Sander, Michael, Institute of Biogeochemistry and Pollutant Dynamics (IBP), Swiss Federal Institute of Technology (ETH) Zürich, Universitätsstr. 16, 8092 Zürich, Switzerland; Hofstetter, Thomas B., Institute of Biogeochemistry and Pollutant Dynamics (IBP), Swiss Federal Institute of Technology (ETH) Zürich, Universitätsstr. 16, 8092 Zürich, Switzerland, Eawag, Swiss Federal Institute of Aquatic Science and Technology, Überlandstr. 133, 8600 Dübendorf, Switzerland / http://dx.doi.org/10.1021/bk-2011-1071.ch017

Reactivity of Zerovalent Metals in Aquatic Media: Effects of Organic Surface Coatings / Tratnyek, Paul G., Division of Environmental and Biomolecular Systems, Oregon Health & Science University, 20000 NW Walker Road, Beaverton, OR 97006; Salter-Blanc, Alexandra J., Division of Environmental and Biomolecular Systems, Oregon Health & Science University, 20000 NW Walker Road, Beaverton, OR 97006; Nurmi, James T., Division of Environmental and Biomolecular Systems, Oregon Health & Science University, 20000 NW Walker Road, Beaverton, OR 97006; Amonette, James E., Fundamental and Computational Sciences Directorate, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352; Liu, Juan, Fundamental and Computational Sciences Directorate, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352; Wang, Chongmin, Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352; Dohnalkova, Alice, Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352; Baer, Donald R., Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352 / http://dx.doi.org/10.1021/bk-2011-1071.ch018

Current Perspectives on the Mechanisms of Chlorohydrocarbon Degradation in Subsurface Environments: Insight from Kinetics, Product Formation, Probe Molecules, and Isotope Fractionation / Elsner, Martin, Helmholtz Zentrum München, German Research Center for Environmental Health (GmbH), Ingolstaedter Landstr. 1 85764 Neuherberg, Germany; Hofstetter, Thomas B., Swiss Federal Institute of Aquatic Science and Technology (Eawag), Überlandstr. 133, 8600 Dübendorf, Switzerland / http://dx.doi.org/10.1021/bk-2011-1071.ch019

Degradation Routes of RDX in Various Redox Systems / Halasz, Annamaria; Hawari, Jalal / http://dx.doi.org/10.1021/bk-2011-1071.ch020

Role of Coupled Redox Transformations in the Mobilization and Sequestration of Arsenic / Hering, Janet G., Eawag, Swiss Federal Institute of Aquatic Science and Technology, CH-8600 Dübendorf, Switzerland; Hug, Stephan J., Eawag, Swiss Federal Institute of Aquatic Science and Technology, CH-8600 Dübendorf, Switzerland; Farnsworth, Claire, Division of Engineering and Applied Sciences, California Institute of Technology, Pasadena CA 91125; O'Day, Peggy A., School of Natural Sciences, University of California, Merced, 95343 / http://dx.doi.org/10.1021/bk-2011-1071.ch021

Redox Processes Affecting the Speciation of Technetium, Uranium, Neptunium, and Plutonium in Aquatic and Terrestrial Environments / O'Loughlin, Edward J., Biosciences Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439; Boyanov, Maxim I., Biosciences Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439; Antonopoulos, Dionysios A., Biosciences Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, The Institute for Genomics and Systems Biology, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439; Kemner, Kenneth M., Biosciences Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439 / http://dx.doi.org/10.1021/bk-2011-1071.ch022

Rate Controlling Processes in the Transformation of Tetrachloroethylene and Carbon Tetrachloride under Iron Reducing and Sulfate Reducing Conditions / Butler, Elizabeth C., School of Civil Engineering and Environmental Science, University of Oklahoma, 202 W. Boyd, Room 334, Norman, OK 73019, USA; Dong, Yiran, School of Civil Engineering and Environmental Science, University of Oklahoma, 202 W. Boyd, Room 334, Norman, OK 73019, USA, Current address: Energy Biosciences Institute, University of Illinois-Urbana Champaign, 1206 W. Gregory Drive, Urbana, IL 61801, USA; Krumholz, Lee R., Department of Botany and Microbiology and Institute for Energy and the Environment, University of Oklahoma, 770 Van Vleet Oval, Norman, OK 73019, USA; Liang, Xiaoming, School of Civil Engineering and Environmental Science, University of Oklahoma, 202 W. Boyd, Room 334, Norman, OK 73019, USA, Current address: Department of Geology, University of Toronto, 22 Russell Street Toronto, ON, M5S 3B1, Canada; Shao, Hongbo, School of Civil Engineering and Environmental Science, University of Oklahoma, 202 W. Boyd, Room 334, Norman, OK 73019, USA, Current address: Geosciences Group, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, USA; Tan, Yao, School of Civil Engineering and Environmental Science, University of Oklahoma, 202 W. Boyd, Room 334, Norman, OK 73019, USA, Current address: Foreign Economic Cooperation Office, Ministry of Environmental Protection, Houyingfanghutong #5, Xicheng District, Beijing, 100035, People's Republic of China / http://dx.doi.org/10.1021/bk-2011-1071.ch023

The Use of Chemical Probes for the Characterization of the Predominant Abiotic Reductants in Anaerobic Sediments / Zhang, Huichun (Judy), Department of Civil and Environmental Engineering, Temple University, 1947 N. 12th Street, Philadelphia, PA 19122; Colón, Dalizza, Ecosystems Research Division, National Exposure Research Laboratory, US Environmental Protection Agency, 960 College Station Rd, Athens, GA 30605; Kenneke, John F., Ecosystems Research Division, National Exposure Research Laboratory, US Environmental Protection Agency, 960 College Station Rd, Athens, GA 30605; Weber, Eric J., Ecosystems Research Division, National Exposure Research Laboratory, US Environmental Protection Agency, 960 College Station Rd, Athens, GA 30605 / http://dx.doi.org/10.1021/bk-2011-1071.ch024

The Role of Transport in Aquatic Redox Chemistry / Kurtz, Wolfgang; Peiffer, Stefan / http://dx.doi.org/10.1021/bk-2011-1071.ch025

Evolution of Redox Processes in Groundwater / McMahon, Peter B., U.S. Geological Survey, Denver Federal Center, Mail Stop 415, Lakewood, CO 80225; Chapelle, Francis H., U.S. Geological Survey, 720 Gracern Rd., Suite 129, Columbia, SC 29210; Bradley, Paul M., U.S. Geological Survey, 720 Gracern Rd., Suite 129, Columbia, SC 29210 / http://dx.doi.org/10.1021/bk-2011-1071.ch026

Editors' Biographies / http://dx.doi.org/10.1021/bk-2011-1071.ot001

Groundwater > Carbon content.

Water > Dissolved oxygen.

Aquatic habitats > Environmental aspects > Analysis.

Oxidation-reduction reaction > Thermodynamics.

Halides > Oxidation.

Halogens > Environmental aspects.

Chemical structure > Models.

Biomass > Analysis.

Iron > Corrosion > Effect of light on.

Iron > Oxidation.

Titanium dioxide > Environmental aspects.

Water > Purification > Photocatalysis > Analysis.

Water > Purification > Disinfection.

Water > Purification > Chlorination.

Water > Pollution.

Water > Purification.

Nanoparticles > Electric properties.

Water > Purification > Iron removal.

Gas-liquid interfaces > Models.

Stable isotopes > Fracture.

Smectite > Analysis.

Chlorohydrocarbons > Biodegradation > Mechanism of action > Analysis.

RDX (Cyclonite) > Deterioration.

Arsenic > Separation.

Transuranium elements > Speciation.

Tetrachloroethylene > Reduction.

Carbon tetrachloride > Reduction.

Sediments (Geology) > Analysis.

Water chemistry > Transport properties.

Groundwater recharge > Analysis.

Groundwater.

Carbon.

Oxidation-Reduction.

Water - chemistry.

Water.

Oxygen.

Ecosystem.

Fresh Water.

Saline Waters.

Thermodynamics.

Halogens - metabolism.

Halogens - adverse effects.

Environmental Pollutants.

Models, Chemical.

Electron Transport.

Energy Transfer.

Biomass.

Electrochemistry.

Iron.

Corrosion.

Light.

Iron - metabolism.

Titanium - adverse effects.

Environment Pollutants.

Water Purification - methods.

Catalysis.

Disinfection.

Waste Disposal, Fluid.

Halogenation.

Water Pollution.

Water Purification.

Nanoparticles.

Electricity.

Electrochemical Techniques.

Surface Tension.

Surface-Active Agents.

Models, Theoretical.

Isotopes.

Silicates - analysis.

Surface Properties.

Hydrocarbons, Chlorinated - metabolism.

Triazines - metabolism.

Arsenic - isolation & purification.

Elements, Radioactive.

Tetrachloroethylene - metabolism.

Carbon Tetrachloride - metabolism.

Geologic Sediments - analysis.

American Chemical Society. Division of Geochemistry, sponsoring body.

American Chemical Society. Division of Environmental Chemistry, sponsoring body.