9783527680986

3527680985

9783527681013

3527681019

9783527336883

Electronic reproduction. Hoboken, N.J. Available via World Wide Web.

Description based on online resource; title from digital title page (viewed on October 03, 2016).

Cover; Title Page; Copyright; Contents; Chapter 1 Oxidative Coupling-Bonding between Two Nucleophiles; 1.1 Introduction/General; 1.1.1 What is Oxidative Cross-Coupling?; 1.1.2 Why Oxidative Cross-Coupling?; 1.1.3 How Does Oxidative Cross-Coupling Work?; 1.1.4 Development and Outlook; References; Chapter 2 Organometals as Nucleophiles; 2.1 Classification and Applications of Organometallic Reagents; 2.2 Csp-M and Csp-M as Nucleophiles; 2.2.1 Alkyne-Alkyne Oxidative Coupling; 2.2.1.1 Alkynyl-Si; 2.2.1.2 Alkynyl-Sn; 2.2.1.3 Alkynyl-B; 2.2.1.4 Alkynyl-Mg; 2.2.1.5 Alkynyl-Te

2.2.2 Alkyne-Cyano Oxidative Coupling2.3 Csp-M and Csp2-M as Nucleophiles; 2.4 Csp-M and Csp3-M as Nucleophiles; 2.5 Csp2-M and Csp2-M as Nucleophiles; 2.5.1 Homocoupling of Csp2-M; 2.5.2 Cross-Coupling between Different Species of Csp2-M; 2.6 Csp2-M and Csp3-M as Nucleophiles; 2.7 Csp3-M and Csp3-M as Nucleophiles; 2.8 Conclusions; References; Chapter 3 Oxidative Couplings Involving the Cleavage of C-H Bonds; 3.1 Theoretical Understandings and Methods in C-H Bond Functionalization; 3.1.1 Introduction; 3.1.2 Mechanisms of C-H Cleavage by Transition Metals; 3.1.2.1 Oxidative Addition

3.1.2.2 Electrophilic Substitution3.1.2.3 -Bond Metathesis; 3.1.2.4 Concerted Metalation Deprotonation (CMD); 3.1.2.5 1,2-Addition; 3.1.2.6 Biomimetic C-H Oxidation; 3.1.2.7 Carbenoid/Nitrenoid C-H Insertion; 3.1.3 Methods for Selective C-H Bond Functionalization; 3.1.3.1 Directed C-H Functionalization; 3.1.3.2 Sterically Controlled C-H Functionalization; 3.1.3.3 C-H Functionalization via Ionic Intermediates; 3.1.3.4 C-H Functionalization via Radical Intermediates; 3.2 Oxidative Couplings between Organometals and Hydrocarbons; 3.2.1 C(sp)-H and Organometals as Nucleophiles

3.2.2 Csp2-H and Organometals as Nucleophiles3.2.3 Csp3-H and Organometals as Nucleophiles; 3.3 Oxidative Couplings between Two Hydrocarbons; 3.3.1 C(sp)-H and C(sp)-H as Nucleophiles; 3.3.2 C(sp)-H and C(sp2)-H as Nucleophiles; 3.3.3 C(sp)-H and C(sp3)-H as Nucleophiles; 3.3.4 Csp2-H and Csp2-H as Nucleophiles; 3.3.4.1 Oxidative Coupling between Directing-Group-Containing Arenes and Unactivated Arenes; 3.3.4.2 Oxidative Coupling of Arenes without Directing Groups; 3.3.4.3 Intramolecular Oxidative Coupling of Unactivated Arenes; 3.3.4.4 Oxidative Heck-Type Cross-Coupling

3.3.5 Csp2-H and Csp3-H as Nucleophiles3.3.5.1 Intramolecular Oxidative Coupling between Aromatic Csp2-H and Csp3-H; 3.3.5.2 Intramolecular Oxidative Coupling between Alkene Csp2-H and Csp3-H; 3.3.5.3 Intermolecular Oxidative Coupling between Csp2-H and Csp3-H; 3.3.6 C(sp3)-H and C(sp3)-H as Nucleophiles; 3.4 Conclusions; References; Chapter 4 Bonding Including Heteroatoms via Oxidative Coupling; 4.1 Introduction; 4.2 Oxidative C-O Bond Formation; 4.2.1 C-H and O-M as Nucleophiles; 4.2.2 C-H and O-H as Nucleophiles; 4.2.2.1 C(sp2, Aryl)-O Bond Formation