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Electronic Communication in Heterometallated Porphyrin Oligomers
Author
Title
Electronic Communication in Heterometallated Porphyrin Oligomers [electronic resource] / by Jonathan Cremers.
ISBN
9783030391010
Edition
1st ed. 2020.
Publication
Cham : Springer International Publishing : Imprint: Springer, 2020.
Physical Description
1 online resource (XLI, 255 p.) 350 illus., 334 illus. in color.
Local Notes
Access is available to the Yale community.
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Access restricted by licensing agreement.
Summary
This book cuts across the divisions of organic, inorganic, and physical chemistry. It describes new methods for creating π-conjugated porphyrin oligomers with precisely defined sequences of zinc and copper metal cations, and how EPR spectroscopy was used to investigate the dipolar and exchange coupling between the paramagnetic copper(II) centres. Porphyrins are a group of heterocyclic macrocycle organic compounds that play an important role in our everyday life and can for example be found in blood where they form a red complex with iron (haem). Various metallic elements can be inserted into a porphyrin and changing the coordinated metal is an excellent way to influece the chemical and physical properties of these molecules. Focusing on 3 metals - zinc, magnesium and copper - the author established new methods for creating π-conjugated porphyrin oligomers and lastly presents the synthesis and investigation of two novel porphyrin nanoballs.Giving the template-directed strategy the author developed for constructing these molecules, this work could provide access to other related nano-cages.
Variant and related titles
Springer ENIN.
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Printed edition:
Format
Books / Online
Language
English
Added to Catalog
February 18, 2020
Series
Springer Theses, Recognizing Outstanding Ph.D. Research,
Contents
Introduction
10-Porphyrin Nanorings with Copper(II) and Zinc(II) Centres
Constructive Quantum Interference in a Heterometallated Porphyrin Nanoring
Synthesis of Ortho, Meta and Para Bis-Copper Porphyrin Nanorings
The Template-Directed Synthesis of a Fully Conjugated 14-Porphyrin Nanoball
The Synthesis of a D4h Symmetric Porphyrin Nanoball using Selective Demetallation.
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