"Presented at the 5th International Symposium on the Chemistry and Biological Chemistry of Vanadium held September 10-14, 2006 at San Francisco, CA as part of the National ACS Meeting"--Page xi.

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ACS symposium series, 974

Synthetic Transformations via Vanadium-Induced Redox Reactions / Hirao, Toshikazu / http://dx.doi.org/10.1021/bk-2007-0974.ch001

Vanadium-Catalyzed Oxidation in Ionic Liquids / Conte, Valeria, Corresponding author: valeria.conte@uniroma2.it; Floris, Barbara; Silvagni, Adriano / http://dx.doi.org/10.1021/bk-2007-0974.ch002

The Synthesis of Functionalized Tetrahydrofurans via Vanadium(V)-Catalyzed Oxidation of Alkenols / Hartung, Jens; Ludwig, Arne; Demary, Mario; Stapf, Georg / http://dx.doi.org/10.1021/bk-2007-0974.ch003

Vanadium-Catalyzed Alkane Functionalization Reactions under Mild Conditions / Pombeiro, Armando J. L. / http://dx.doi.org/10.1021/bk-2007-0974.ch004

Biomimetic Vanadium Complexes and Oxo Transfer Catalysis / Wu, Pingsong; Santoni, Gabriella; Wikete, Cornelia; Olbrich, Falk; Rehder, Dieter / http://dx.doi.org/10.1021/bk-2007-0974.ch005

Coordination Chemistry and Applications of Vanadium Alkoxides in Catalysis / Rosenthal, Esther C. E.; Cui, Huiling; Koch, Juliane / http://dx.doi.org/10.1021/bk-2007-0974.ch006

Enhancement of Insulin Action by bis(Acetylacetonato)oxovanadium(IV) Occurs through Uncompetitive Inhibition of Protein Tyrosine Phosphatase-1B / Makinen, Marvin W., Department of Biochemistry and Molecular Biology, Gordon Center for Integrative Science, The University of Chicago, 929 East 57 Street, Chicago, IL 60637; Rivera, Stephanie E., Department of Biochemistry and Molecular Biology, Gordon Center for Integrative Science, The University of Chicago, 929 East 57 Street, Chicago, IL 60637; Zhou, Katherine I., Department of Biochemistry and Molecular Biology, Gordon Center for Integrative Science, The University of Chicago, 929 East 57 Street, Chicago, IL 60637; Brady, Matthew J., Department of Medicine and Committee on Molecular Metabolism and Nutrition, The University of Chicago, 5841 South Maryland Avenue, Chicago, IL 60637 / http://dx.doi.org/10.1021/bk-2007-0974.ch007

Comparing Administration Route in Rats with Streptozocin-Induced Diabetes and Inhibition of Myoblast Growth of Vanadium [V(III), V(IV), and V(V)] Dipicolinic Acid Complexes / Willsky, Gail R., Department of Biochemistry, University at Buffalo (SUNY), Buffalo, NY 14214; Godzalla, Michael E., Department of Biochemistry, University at Buffalo (SUNY), Buffalo, NY 14214, Department of Pharmacology, University at Buffalo (SUNY), Buffalo, NY 14214; Kostyniak, Paul J., Department of Pharmacology, University at Buffalo (SUNY), Buffalo, NY 14214; Chi, Lai-Har, Department of Biochemistry, University at Buffalo (SUNY), Buffalo, NY 14214; Gupta, Rohit, Department of Biochemistry, University at Buffalo (SUNY), Buffalo, NY 14214; Yuen, Violet G., Faculty of Pharmaceutical Sciences, University of British Columbia, Vancouver, Canada; McNeill, John H., Faculty of Pharmaceutical Sciences, University of British Columbia, Vancouver, Canada; Mahroof-Tahir, Mohammad, Department of Chemistry, Colorado State University, Fort Collins, CO 80523; Smee, Jason J., Department of Chemistry, Colorado State University, Fort Collins, CO 80523; Yang, Luqin, Department of Chemistry, Colorado State University, Fort Collins, CO 80523; Lobernick, Aaron, Department of Chemistry, Colorado State University, Fort Collins, CO 80523; Watson, Shari, Department of Chemistry, Colorado State University, Fort Collins, CO 80523; Crans, Debbie C., Department of Chemistry, Colorado State University, Fort Collins, CO 80523 / http://dx.doi.org/10.1021/bk-2007-0974.ch008

Structure-Activity Relationship and Molecular Action Mechanism in the Family of Antidiabetic bis(Picolinato)oxovanadium(IV) Complexes / Sakurai, Hiromu / http://dx.doi.org/10.1021/bk-2007-0974.ch009

Do Vanadium Compounds Drive Reorganization of the Plasma Membrane and Activation of Insulin Receptors with Lipid Rafts? / Roess, Deborah A.; Smith, Steven M. L.; Holder, Alvin A.; Baruah, Bharat; Trujillo, Alejandro M.; Gilsdorf, Daniel; Stahla, Michelle L.; Crans, Debbie C. / http://dx.doi.org/10.1021/bk-2007-0974.ch010

Structural Studies of Vanadium Haloperoxidases: Insight into Halide Specificity, Stability, and Enzyme Mechanism / Littlechild, Jennifer; Garcia-Rodriguez, Esther; Coupe, Elizabeth; Watts, Aaron; Isupov, Mikail / http://dx.doi.org/10.1021/bk-2007-0974.ch011

Understanding the Mechanism of Vanadium-Dependent Haloperoxidases and Related Biomimetic Catalysis / Schneider, Curtis J., Department of Chemistry, University of Michigan, Ann Arbor, MI 48109-1055; Zampella, Giuseppe, Department of Biotechnology and Biosciences, University of Milano-Bicocca, Piazza della Scienza 2, 20126, Milano, Italy; DeGioa, Luca, Department of Biotechnology and Biosciences, University of Milano-Bicocca, Piazza della Scienza 2, 20126, Milano, Italy; Pecoraro, Vincent L., Department of Biotechnology and Biosciences, University of Milano-Bicocca, Piazza della Scienza 2, 20126, Milano, Italy, Biophysics Research Division, University of Michigan, Ann Arbor, MI 48109-1055 / http://dx.doi.org/10.1021/bk-2007-0974.ch012

Model Studies of Vanadium-Dependent Haloperoxidation: Structural and Functional Lessons: Synthetic and Computational Models of Supramolecular Interactions and the Formation of Peroxo Species / Plass, Winfried; Bangesh, Masroor; Nica, Simona; Buchholz, Axel / http://dx.doi.org/10.1021/bk-2007-0974.ch013

51V Solid-State NMR Spectroscopy of Vanadium Haloperoxidases and Bioinorganic Haloperoxidase Mimics / Polenova, Tatyana, Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716; Pooransingh-Margolis, Neela, Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716; Rehder, Dieter, Institut für Anorganische und Angewandte Chemie, Universität Hamburg,D-20146 Hamburg, Germany; Renirie, Rokus, Van't Hoff Institute for Molecular Sciences, Faculty of Science, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands; Wever, Ron, Van't Hoff Institute for Molecular Sciences, Faculty of Science, University of Amsterdam, Nieuwe Achtergracht 129, 1018 WS Amsterdam, The Netherlands / http://dx.doi.org/10.1021/bk-2007-0974.ch014

Vanadium and Bone: Relevance of Vanadium Compounds in Bone Cells / Etcheverry, Susana B., Cátedra de Bioqu´mica Patológica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina, Centro de Química Inorgánica (CEQUINOR), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina; Barrio, Daniel A., Cátedra de Bioqu´mica Patológica, Facultad de Ciencias Exactas, Universidad Nacional de La Plata, La Plata, Argentina / http://dx.doi.org/10.1021/bk-2007-0974.ch015

Toxicity of Vanadium Compounds: Pulmonary and Immune System Targets / Cohen, Mitchell D. / http://dx.doi.org/10.1021/bk-2007-0974.ch016

Biological Effects of Vanadium in the Lung / Ghio, Andrew J.; Samet, James M. / http://dx.doi.org/10.1021/bk-2007-0974.ch017

Biological Effects of Decavanadate: Muscle Contraction, In Vivo Oxidative Stress, and Mitochondrial Toxicity / Aureliano, Manuel, CCMAR, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal, Departamento de Química y Bioquímica, Faculdade de Ciências e Tecnologia, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal, Corresponding author: University of Algarvbe, 8005-139 Faro, Portugal (maalves@ualg.pt); Soares, Sandra S., CCMAR, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal, Faculdade de Ciências do Mar e do Ambiente, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal; Tiago, Teresa, CCMAR, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal, Departamento de Química y Bioquímica, Faculdade de Ciências e Tecnologia, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal; Ramos, Susana, CCMAR, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal, Departamento de Química y Bioquímica, Faculdade de Ciências e Tecnologia, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro, Portugal; Gutiérrez-Merino, Carlos, Departamento de Bioquímica y Biología Molecular, Facultad de Ciencias, Universidad de Extremadura, Av. Elvas s/n, 06071 Badajoz, Spain / http://dx.doi.org/10.1021/bk-2007-0974.ch018

Genes and Proteins Involved in Vanadium Accumulation by Ascidians / Michibata, Hitoshi, Department of Biological Science, Graduate School of Science, Hiroshima University, Higashi-Hiroshima 1-3-1, Hiroshima 739-8526, Japan; Yoshinaga, Masafumi, Department of Biological Science, Graduate School of Science, Hiroshima University, Higashi-Hiroshima 1-3-1, Hiroshima 739-8526, Japan; Yoshihara, Masao, Department of Biological Science, Graduate School of Science, Hiroshima University, Higashi-Hiroshima 1-3-1, Hiroshima 739-8526, Japan; Kawakami, Norifumi, Department of Biological Science, Graduate School of Science, Hiroshima University, Higashi-Hiroshima 1-3-1, Hiroshima 739-8526, Japan; Yamaguchi, Nobuo, Marine Biological Laboratory, Graduate School of Science, Hiroshima University, Mukaishima 2445, Hiroshima 722-0073, Japan; Ueki, Tatsuya, Department of Biological Science, Graduate School of Science, Hiroshima University, Higashi-Hiroshima 1-3-1, Hiroshima 739-8526, Japan / http://dx.doi.org/10.1021/bk-2007-0974.ch019

Toward the Biological Reduction Mechanism of Vanadyl Ion in the Blood Cells of Vanadium-Sequestering Tunicates / Frank, Patrick, Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94309, The Department of Chemistry, Stanford University, Stanford, CA 94305-5080, Corresponding author: telephone: 1-650-723-2479; fax: 1-650-723-4817; email: frank@ssrl.slac.stanford.edu; Carlson, Elaine J., The Buck Institute, Novato, CA 94945, Current address: Department of Biochemistry and Biophysics, University of California, San Francisco, CA 94143-0984; Carlson, Robert M. K., The Chevron Energy Technology Company, P.O. Box 1627, Richmond, CA 94802; Hedman, Britt, Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94309; Hodgson, Keith O., Stanford Synchrotron Radiation Laboratory, SLAC, Stanford University, Stanford, CA 94309, The Department of Chemistry, Stanford University, Stanford, CA 94305-5080 / http://dx.doi.org/10.1021/bk-2007-0974.ch020

Chemical and Biochemical Insights on Preventing Cancer with Vanadium and Selenium / Hamilton, Elizabeth E.; Fautch, Jessica M.; Gentry, Sarah M.; Wilker, Jonathan J. / http://dx.doi.org/10.1021/bk-2007-0974.ch021

Speciation of Peroxovanadium(V) Complexes Studied by First-Principles Molecular Dynamics Simulations and 51V NMR Chemical Shift Computations / Bühl, Michael / http://dx.doi.org/10.1021/bk-2007-0974.ch022

Biospeciation of Insulin-Mimetic VO(IV) Complexes / Kiss, Tamás, Department of Inorganic and Analytical Chemistry, University of Szeged, P.O. Box 440, Szeged, H-6701, Hungary, Bioinorganic Chemistry Research Group of the Hungarian Academy of Sciences, University of Szeged, P.O. Box 440, Szeged, H-6701, Hungary; Jakusch, Tamás, Bioinorganic Chemistry Research Group of the Hungarian Academy of Sciences, University of Szeged, P.O. Box 440, Szeged, H-6701, Hungary; Hollender, Dominik, Bioinorganic Chemistry Research Group of the Hungarian Academy of Sciences, University of Szeged, P.O. Box 440, Szeged, H-6701, Hungary; Dönyei, Ágnes, Department of Inorganic and Analytical Chemistry, University of Szeged, P.O. Box 440, Szeged, H-6701, Hungary / http://dx.doi.org/10.1021/bk-2007-0974.ch023

Vanadium Schiff Base Complexes: Chemistry, Properties, and Concerns about Possible Therapeutic Applications / Pessoa, João Costa, Instituto Superior Técnico, Centro Química Estrutural, Av. Rovisco Pais, 1049-001 Lisboa, Portugal; Cavaco, I., Instituto Superior Técnico, Centro Química Estrutural, Av. Rovisco Pais, 1049-001 Lisboa, Portugal; Correia, I., Instituto Superior Técnico, Centro Química Estrutural, Av. Rovisco Pais, 1049-001 Lisboa, Portugal; Tomaz, I., Instituto Superior Técnico, Centro Química Estrutural, Av. Rovisco Pais, 1049-001 Lisboa, Portugal; Adão, P., Instituto Superior Técnico, Centro Química Estrutural, Av. Rovisco Pais, 1049-001 Lisboa, Portugal; Vale, I., Instituto Superior Técnico, Centro Química Estrutural, Av. Rovisco Pais, 1049-001 Lisboa, Portugal; Ribeiro, V., Centro de Biomedicina Molecular e Estrutural, Universidade do Algarve, Faro, Portugal; Castro, M. M. C. A., Departmento de Bioquímica, Faculdade de Ciências e Tecnologia e Centro de Neurociências de Coimbra, Universidade de Coimbra, P.O. Box 3126, 3001-401 Coimbra, Portugal; Geraldes, C. C. F. G., Departmento de Bioquímica, Faculdade de Ciências e Tecnologia e Centro de Neurociências de Coimbra, Universidade de Coimbra, P.O. Box 3126, 3001-401 Coimbra, Portugal / http://dx.doi.org/10.1021/bk-2007-0974.ch024

Charge Distribution in Vanadium p-(Hydro/Semi)Quinonate Complexes / Drouza, Chryssoula; Keramidas, Anastasios D., Corresponding author: email: akeramid@ucy.ac.cy / http://dx.doi.org/10.1021/bk-2007-0974.ch025

Electron Spin Lattice Relaxation of V(IV) Complexes in Glassy Solutions between 15 and 70 K / Fielding, Alistair J., Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208-2436; Back, Dong Bin, Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208-2436; Engler, Michael, Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208-2436; Baruah, Bharat, Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872; Crans, Debbie C., Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872; Eaton, Gareth R., Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208-2436; Eaton, Sandra S., Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208-2436 / http://dx.doi.org/10.1021/bk-2007-0974.ch026

Synthetic and Structural Studies of Aqueous Vanadium(IV,V) Hydroxycarboxylate Complexes / Salifoglou, Athanasios / http://dx.doi.org/10.1021/bk-2007-0974.ch027

Structural Determinants in the Oxovanadium Diphosphonate System / Ouellette, Wayne; Zubieta, Jon / http://dx.doi.org/10.1021/bk-2007-0974.ch028

Stepwise Synthesis of Disk- and Ball-Shaped Polyoxovanadates: All-Inorganic Coordination Chemistry of Polyoxovanadates / Hayashi, Yoshihito; Shinguchi, Takayuki; Kurata, Taisei; Isobe, Kiyoshi / http://dx.doi.org/10.1021/bk-2007-0974.ch029

A Vanadium-Based Homogeneous Chemical Oscillator / Kanamori, Kan; Shirosaka, Yuya / http://dx.doi.org/10.1021/bk-2007-0974.ch030

Vanadium > Synthesis.

Ionic solutions > Oxidation.

Tetrahydrofuran > Synthesis.

Insulin > Mechanism of action > Technological innovations.

Myoblasts > Chemical inhibitors.

Hypoglycemic agents > Mechanism of action.

Hypoglycemic agents > Structure-activity relationships.

Insulin > Receptors > Effect of drugs on.

Peroxidase > Structure > Analysis.

Macromolecules > Models.

Vanadium > Spectra.

Bone cells > Composition > Analysis.

Vanadium compounds > Toxicology.

Vanadium compounds > Physiological effect.

Sea squirts > Bioaccumulation.

Tunicata > Biological control.

Cancer > Chemoprevention.

Vanadium compounds > Molecular aspects > Computer simulation.

Schiff bases > Analysis.

Schiff bases > Therapeutic use.

Vanadium compounds > Electric properties.

Vanadium compounds > Structure.

Vanadium compounds > Synthesis.

Diphosphonates > Structure > Analysis.

Vanadates > Synthesis.

Oscillating chemical reactions > Materials.

Organometallic Compounds.

Vanadium.

Catalysis.

Vanadium Compounds.

Vanadium - chemical synthesis.

Oxidation-Reduction.

Ionic Liquids - metabolism.

Furans - chemical synthesis.

Biomimetic Materials.

Insulin - pharmacology.

Iventions.

Myoblasts.

Hypoglycemic Agents - pharmacology.

Hypoglycemic Agents.

Structure-Activity Relationship.

Receptor, Insulin - antagonists & inhibitors.

Peroxidase - analysis.

Macromolecular Substances - chemistry.

Macromolecular Substances.

Models, Theoretical.

Magnetic Resonance Spectroscopy.

Bone and Bones - cytology.

Vanadium Compounds - toxicity.

Urochordata.

Pest Control, Biological.

Neoplasms.

Chemoprevention.

Computer Simulation.

Schiff Bases - analysis.

Schiff Bases - therapeutic use.

Electricity.

Physical Phenomena.

Vanadium Compounds - chemical synthesis.

Diphosphonates - chemistry.

Vanadates - chemical synthesis.

Chemical Phenomena.

American Chemical Society. Division of Inorganic Chemistry, sponsoring body.

American Chemical Society. Meeting (232nd : 2006 : San Francisco, California)

International Symposium on the Chemistry and Biological Chemistry of Vanadium (5th : 2006 : San Francisco, California)